FACULTY
PUBLICATIONS
ASTRONOMY
The Cosmos: Astronomy in the New Millennium
Pasachoff, Jay M., and Alex Filippenko
A general survey textbook on astronomy
Teaching and Learning of Astronomy: Effective Strategies
for Educators Worldwide
Pasachoff, Jay M., and John R. Percy
Charon’s Radius and Atmospheric Constraints from
the Stellar Occultation Observations
Gulbis, A. A. S., J. L. Elliot, M. J. Person, and E.R. Adams
(MIT), B. A. Babcock (Williams),
M. Emilio (Univ. Estadual de Ponta Grossa,
Brazil), J. W. Gangestad (Williams), S.D. Kern and E. A. Kramer (MIT),
D. J.
Osip (Observatories of the Carnegie Institution of Washington),
J. M.
Pasachoff and S. P. Souza (Williams College), and T. Tuvikene (Vrije Univ.,
Belgium)
Nature; Jan. 5, 2006, issue, 439, pp. 48-51
The physical characteristics of Pluto and its moon, Charon, provide insight
into the evolution of the outer Solar System. Although previous measurements
have constrained the masses of these bodies, their radii and densities have
remained uncertain. The observation of a stellar occultation by Charon in 1980
established a lower limit on its radius of 600 km (later refined to 601.5 km)
and suggested a possible atmosphere. Subsequent, mutual event modeling yielded
a range of 600-650 km, corresponding to a density of 1.56 ± 0.22 g
cm
-3. Here we report multiple-station observations of a stellar
occultation by Charon. From these data, we find a mean radius of 606 ± 8
km, a bulk density of 1.72 ± 0.15 g cm
-3, and rock-mass fraction
0.63 ± 0.05. We do not detect a significant atmosphere and place 3-sigma
upper limits on atmospheric number densities for candidate gases. These results
seem to be consistent with collisional formation for the Pluto—Charon
system in which the precursor objects may have been differentiated, and they
leave open the possibility of atmospheric retention by the largest objects in
the outer solar system.
[See
http://www.nature.com/nature/journal/v439/n7072/full/nature04276.html
, analyzed in:
http://www.nature.com/nature/journal/v439/n7072/full/439024a.html
The Effect of the Transit of Venus on ACRIM’s Total
Solar Irradiance
Measurements: Implications for Transit Studies of
Extrasolar Planets
Schneider, G., J. M. Pasachoff, and Richard C. Willson,
2006
Astrophys. J. 641, 565-571 (April 10)
We have used the 2004 June 8 transit of Venus (ToV) as a surrogate to test
observing methods, strategies, and techniques that are being contemplated for
future space missions to detect and characterize extrasolar terrestrial planets
(ETPs) as they transit their host stars, notably NASA’s Kepler mission,
planned for 2008. As an analog to “Kepler-like” photometric transit
observations, we obtained (spatially unresolved) radiometric observations with
the ACRIM 3 instrument on board ACRIMSAT at a sampling cadence of 131 s to
follow the effect of the ToV on the total solar irradiance (TSI).
Contemporaneous high-resolution broadband imagery with NASA’s TRACE
spacecraft provided, directly, measures of the stellar (solar) astrophysical
noise that can intrinsically limit such transit observations. During the Venus
transit, which lasted 5.5 hr, the planet’s angular diameter was
approximately 1/32 the solar diameter, thus covering 0.1% of the stellar
surface. With our ACRIM 3 data, we measure temporal changes in TSI with a 1
sigma per sample (unbinned) uncertainty of approximately 100 mW m-2
(0.007%). A diminution in TSI of 1.4 W m-2 (0.1%, closely
corresponding to the geometrically occulted area of the photosphere) was
measured at mid-transit compared with a mean pre-/post-transit TSI of 1365.9 W
m-2. The radiometric light curve is complex because of the
parallactic motion of Venus induced by ACRIMSAT’s near-polar orbit, but
exhibits the characteristic signature of photospheric limb darkening. These
observations serve as a surrogate for future photometric observations of ETPs,
such as Kepler will deliver. Detailed analysis of the ToV, a rare event within
our own solar system, with time-resolved radiometry augmented with
high-resolution imagery, provides a useful analog for investigating the
detectability and characterization of ETPs from observations that are
anticipated in the near future.
Deuterium in the Galactic Center: Evidence for a
Cosmological Origin of D and the
Infall of D Enriched Gas
Lubowich, D. A., J. M. Pasachoff, H. R. Roberts, T. Millar,
C. Henkel, and G. Brammer
Bull. Am. Astron. Soc. 38, #1, 186
The abundance of deuterium in the center of the Milky Way Galaxy, though
relatively low compared with normal hydrogen, is higher than expected
considering astration. We summarize the evidence and argue that the observed
abundance largely results from in falling gas that is enriched in
deuterium.
Charon’s Radius and Atmospheric Constraints from
Observations of a Stellar Occultation
A.A.S. Gulbis, J.L. Elliot, M.J. Person, E.R. Adams, B.A.
Babcock, M. Emilio, J.W. Gangestad, S.D. Kern, E.A. Kramer, D.J. Osip, J.M.
Pasachoff, S.P. Souza, and T. Tuvikene
Nature, 439, 48-51, 5 January [2006]
The physical characteristics of Pluto and its moon, Charon, provide insight
into the evolution of the outer Solar System. Although previous measurements
have constrained the masses of these bodies, their radii and densities have
remained uncertain. The observation of a stellar occultation by Charon in 1980
established a lower limit on its radius of 600 km (later refined to 601.5 km)
and suggested a possible atmosphere. Subsequent, mutual event modelling yielded
a range of 600–650 km, corresponding to a density of 1.56 ± 0.22 g
cm–3. Here we report multiple-station observations of a stellar
occultation by Charon. From these data, we find a mean radius of 606 ± 8
km, a bulk density of 1.72 ± 0.15 g cm–3, and rock-mass
fraction 0.63 ±0.05. We do not detect a significant atmosphere and place
3-sigma upper limits on atmospheric number densities for candidate gases. These
results seem to be consistent with collisional formation for the
Pluto–Charon system in which the precursor objects may have been
differentiated, and they leave open the possibility of atmospheric retention by
the largest objects in the outer solar system.
The Shaping of Planetary Nebula Sh 2-188 through
Interaction with the Interstellar Medium
Wareing, C.J., O’Brien, T.J., Zijlstra, A.A., Kwitter,
K.B., Irwin, J., and Drew, J.E.
Sh2-188: ISM Shaping in Action, Mon. Not. R.A.S, 366, 387
[2006]
Sh 2-188 is an example of strong interaction between a planetary nebula
(PN) and the interstellar medium (ISM). It shows a single arc-like structure,
consisting of several filaments, which is postulated to be the result of motion
through the ISM. We present new H images from the Isaac Newton
Telescope Photometric H Survey of the Northern Galactic Plane that
reveal structure behind the filamentary limb. A faint, thin arc is seen
opposite the bright limb, in combination forming a closed ring. Behind the
faint arc, a long wide tail is detected, doubling the size of the nebula. The
nebula extends 15 arcmin on the sky in total. We have developed a
‘triple-wind’ hydrodynamical model, comprising of the initial
‘slow’ asymptotic giant branch (AGB) wind and the later
‘fast’ stellar wind (the interacting stellar winds model), plus a
third wind reflecting the motion through the ISM. Simulations at various
velocities of the central star relative to the ISM indicate that a high velocity
of 125 km s-1 is required to reproduce the observed structure. We
find that the bright limb and the tail already formed during the AGB phase,
prior to the formation of the PN. The closure of the ring arises from the
slow-fast wind interaction. Most of the mass lost on the AGB has been swept
downstream, providing a potential explanation of the missing-mass problem in
PNe. We report a proper motion for the central star of 30 ± 10
mas yr-1, the distance to the nebula is estimated to be
850+500-420 pc, consistent with a spectroscopic distance
to the star. Expansion velocities measured from spectroscopic data of the
bright filaments are consistent with velocities measured from the simulation.
Sh 2-188 is one of the largest PNe known, with an extent of 2.8 pc. The model
shows that this size was already set during the AGB phase.
The Helix Nebula – a Swan Song in
Aquarius
Kwitter, K.B.
An essay on the Helix Nebula and current ideas about its history, evolution
and future
Sky & Telescope, ‘Spotlight on...’ essay [November
2005]
BIOLOGY
Hedgehog Regulated Slit Expression Determines Commissure
and Glial Cell
Position in the Zebrafish Forebrain
Barresi, M.J., Hutson, L.D., Assistant Professor, Chien,
C.B., Karlstrom, R.O.
Development, 132(16), 3643-56 (2005)
Three major axon pathways cross the midline of the vertebrate forebrain
early in embryonic development: the postoptic commissure (POC), the anterior
commissure (AC) and the optic nerve. We show that a small population of Gfap+
astroglia spans the midline of the zebrafish forebrain in the position of, and
prior to, commissural and retinal axon crossing. These glial
“bridges” form in regions devoid of the guidance molecules slit2 and
slit3, although a subset of these glial cells express slit1a. We show that Hh
signaling is required for commissure formation, glial bridge formation, and the
restricted expression of the guidance molecules slit1a, slit2, slit3 and sema3d,
but that Hh does not appear to play a direct role in commissural and retinal
axon guidance. Reducing Slit2 and/or Slit3 function expanded the glial bridges
and caused defasciculation of the POC, consistent with a ;channeling' role for
these repellent molecules. By contrast, reducing Slit1a function led to reduced
midline axon crossing, suggesting a distinct role for Slit1a in midline axon
guidance. Blocking Slit2 and Slit3, but not Slit1a, function in the Hh pathway
mutant yot (gli2DR) dramatically rescued POC axon crossing and glial bridge
formation at the midline, indicating that expanded Slit2 and Slit3 repellent
function is largely responsible for the lack of midline crossing in these
mutants. This analysis shows that Hh signaling helps to pattern the expression
of Slit guidance molecules that then help to regulate glial cell position and
axon guidance across the midline of the forebrain.
The Effects of Host-Plant Quality and Ant-Tending for the
Treehopper Publilia concava
Morales, M.A., Assistant Professor, and A.L.H. Beal
’05
Annals of the Entomological Society of America, 99, 545-552
(2006)
Few studies have evaluated the relative importance of bottom-up regulation
for the population dynamics of mutualism. To address this, we tested the
hypothesis that host plant quality affects the strength of the mutualism between
Publilia concava (Say) (Hemiptera: Membracidae) treehoppers
feeding on Solidago altissima L. and ants. P. concava is a
phloem-feeding treehopper that excretes a sugary waste product called honeydew.
Ants collect this honeydew as a food resource, and treehoppers benefit both
directly (e.g., feeding facilitation) and indirectly (e.g., protection from
predators). We evaluated the effect of host plant quality on both the direct and
indirect effects of this mutualism by using a factorial design that manipulated
N-P-K fertilizer level and ant presence. For the experiment that focused on the
direct effects of ant tending, both body size and survivorship were monitored.
For the experiment that included the indirect effects of ant tending, only
survivorship was monitored. Both host plant quality and ant tending increased
the performance (survivorship and size) of Publilia treehoppers. However,
we find no support for the hypothesis that host plant quality influences the
strength of the mutualism in this system - there was no significant interaction
between ant tending and fertilization for any measure of treehopper performance
considered. We suggest that this result is explained by the independence of per
capita tending levels with both host plant quality and treehopper density in
this experiment.
Perinatal MSG Treatment Attenuates Fasting-Induced
Bradycardia and
Metabolic Suppression
M.M. Messina, S.A. Evans, Steven J. Swoap, Associate
Professor, and J.M. Overton
Physiology & Behavior, 86(3), 324-30 (2005)
We studied the effect of arcuate nucleus (ARC) lesions induced
pharmacologically by the perinatal treatment of monosodium L-glutamate
(MSG) on the cardiovascular, metabolic, and behavioral responses to fasting.
Saline and MSG-treated male Sprague-Dawley rats were instrumented with telemetry
devices for measurement of mean arterial pressure (MAP) and heart rate (HR) and
housed in room calorimeters at an ambient temperature (Ta) of
23°C for assessment of oxygen consumption (VO2). At baseline, controls and
MSG-treated rats had similar MAP (control= 95 ± 4; MSG= 91 ± 2 mmHg),
HR (control= 323 ± 4; MSG= 324 ± 2 bpm), and VO2 (control= 8.7 ±
0.3; MSG =8.6 ± 0.2 ml/min). There were no differences in fasting-induced
reductions in body weight or in food intake upon refeeding. MSG-treatment
significantly attenuated fasting-induced reductions in HR and VO2. This effect
was specific to reduced caloric availability, as MSG-treated rats exhibited
intact capacity to both increase and decrease HR and VO2 in response to cold
(Ta=15°C) and to thermoneutrality (Ta=30°C).
Additional studies were performed in saline- and MSG-treated rats chronically
treated with β1-adrenergic receptor blockade (atenolol) prior to and during
fasting. In controls, the cardiovascular responses to fasting during
β1-blockade were blunted and generally mimicked the effects of
MSG-treatment, while β1-blockade had no additional effect on MSG-treated
rats. The results are consistent with the hypothesis that ARC neuronal signaling
is requisite for intact homeostatic responses to fasting and may participate in
fasting-induced withdrawal of cardiac sympathetic activity.
The Full Expression of Fasting-Induced Torpor Requires
β3 Adrenergic Receptor Signaling
Steven J. Swoap, Associate Professor, M.J. Gutilla, L.C.
Liles, R.O Smith ‘05 and D. Weinshenker
Journal of Neuroscience, 26, 241-245 (2006)
Torpor, a controlled rapid drop in metabolic rate and body temperature
(Tb), is a hypometabolic adaptation to stressful environmental
conditions, which occurs in many small mammals, marsupials, and birds. To date,
signaling pathways required for torpor have not been identified. We examined
the role of the sympathetic nervous system (SNS) in mediating the torpor
adaptation to fasting by telemetrically monitoring the Tb of dopamine
beta -hydroxylase knockout (Dbh) -/- mice which lack the ability to
produce the SNS transmitters, norepinephrine (NE) and epinephrine (Epi).
Control (Dbh +/-) mice readily reduced serum leptin levels and entered
torpor after a fast in a cool environment. In contrast, Dbh -/- mice
failed to reduce serum leptin and enter torpor under fasting conditions, whereas
restoration of peripheral but not central NE lowered serum leptin levels and
rescued the torpor response. Torpor was expressed in fasted Dbh -/- mice
immediately after administration of either the non-selective alpha adrenergic
receptor agonist, isoproterenol, or the beta3 AR specific agonist, CL316243, but
not after administration of beta1, beta2, or alpha agonists.
Importantly, the beta3-specific antagonist, SR 59230A, severely blunted
fasting-induced torpor in control mice, whereas other AR antagonists were
ineffective. These results define a critical role of peripheral SNS activity at
beta3 AR-containing tissues in the torpor adaptation to limited energy
availability and cool ambient temperature.
Peripheral Oxyntomodulin Increases Heart Rate in Mice,
Independent of
Insulin and Catecholamines
Sowden, G.L. ’06, Weishenker, D., Swoap, S.J.,
Associate Professor
FASEB Journal, 29(4), A313 Part 1 (2006)
Oxyntomodulin (OXM), a postprandially released gut hormone, inhibits food
intake and stimulates metabolism in humans and rodents. Acting via the GLP-1
receptor, OXM functions as an incretin, stimulating release of insulin, a
hormone known to stimulate the sympathetic nervous system (SNS). Using
telemetry to measure heart rate (HR) in conscious and freely moving mice, we
tested 1) whether OXM affects HR, and 2) whether the HR effects are mediated via
insulin and SNS. Compared with saline, 15 μg of OXM increased HR in C57Bl
mice by 121 ± 19 bpm (P<0.05, n=9) over the first 15 minutes up to 706
± 9 bpm. To test the role of insulin, we administered OXM to
streptazotocin-induced diabetic mice. OXM induced a similar increase in HR in
type-I diabetic mice [an increase of 156 ±18 bpm, (P<0.05, n=9)],
suggesting that the HR effects of OXM are independent of insulin. To test the
hypothesis that the HR effects of OXM are mediated through the SNS, we measured
the HR effects of OXM in Dbh-/- mice that lack epinephrine and
norepinephrine. Dbh-/- mice did not respond to saline injections.
However, Dbh-/- mice demonstrated a vigorous increase in HR within the
first 15 min. after OXM administration [an increase of 164 ± 18 bpm,
(P<0.05, n=6)], suggesting that OXM exerts its effects on HR independent of
catecholamines. From our data, we can conclude that OXM exerts an effect on HR
independent of insulin and SNS, and may act directly on the heart.
Fasting-Induced Torpor Requires Beta 3 Adrenergic
Receptor
Swoap, S.J., Associate Professor, Gutilla, M.J., Liles,
L.C., Smith, R.O. ’05, and Weinshenker, D.
FASEB Journal, 20(5), A828-A829, Part 2 (2006)
Torpor, a controlled rapid drop in metabolic rate and body temperature
(Tb), is a hypometabolic adaptation to stressful environmental conditions,
which occurs in many small mammals, marsupials, and birds. To date,
signaling pathways required for torpor have not been identified. We examined
the role of the sympathetic nervous system (SNS) in mediating the torpor
adaptation to fasting by telemetrically monitoring the Tb of dopamine
beta beta hydroxylase knockout (Dbh) -/- mice which lack the ability to
produce the SNS transmitters, norepinephrine (NE) and epinephrine (Epi).
Control (Dbh +/-) mice readily reduced serum leptin levels and entered
torpor after a fast in a cool environment. In contrast, Dbh -/- mice
failed to reduce serum leptin and enter torpor under fasting conditions,
whereas restoration of peripheral but not central NE lowered serum
leptin levels and rescued the torpor response. Torpor was expressed in
fasted Dbh -/- mice immediately after administration of either the
non-selective alpha adrenergic receptor agonist, isoproterenol, or the
beta3 AR specific agonist, CL316243, but not after administration of beta1,
beta2, or alpha antagonists. Importantly, a beta3-specific antagonist severely
blunted fasting-induced torpor in control mice, whereas other AR
antagonists were ineffective. These results define a critical role of
peripheral SNS activity at beta3 AR-containing tissues in the torpor
adaptation.
CHEMISTRY
Enhanced Antigen Presentation and
Immunostimulation of Dendritic Cells Using Acid-Degradable Cationic
Nanoparticles
Young Jik Kwon, Stephany M. Standley, Sarah L. Goh,
Assistant Professor of Chemistry,
and Jean M. J. Frechet
Journal of Controlled Release, 105, 199-212 (2005)
Acid-degradable cationic nanoparticles encapsulating a model antigen (i.e.,
ovalbumin) were prepared by inverse microemulsion polymerization with
acid-cleavable acetal cross-linkers. Incubation of these degradable
nanoparticles with dendritic cells derived from bone marrow (BMDCs) resulted in
the enhanced presentation of ovalbumin-derived peptides, as quantified by B3Z
cells, a CD8+ T cell hybridoma. The cationic nature of the particles
contributed to the increased surface endocytosis (or phagocytosis) observed with
BMDCs, which is the first barrier to overcome for successful antigen delivery.
The acid sensitivity of the particles served to direct more ovalbumin antigens
to be processed into the appropriately trimmed peptide fragments and presented
via the major histocompatibility complex (MHC) class I pathway following
hydrolysis within the acidic lysosomes. It was also shown that adjuvant
molecules such as unmethylated CpG oligonucleotides (CpG ODN) and
anti-interleukin-10 oligonucleotides (AS10 ODN) could be co-delivered with the
protein antigen for maximized cellular immune response.
Binding of the Bacillus subtilis LexA Protein to
the SOS operator
Eli S. Groban ’02, Martha B. Johnson ’97, Poopak
Banky ’93, Peta-Gaye G. Burnett ’04,
Georgina L. Calderon
’05, Erica C. Dwyer ’03, Shakierah N. Fuller ’04, Biniam Gebre
’00,
Leah M. King ’04, Ila N. Sheren ’05, Lindi D. Von
Mutius ’04, Thomas M. O’Gara,
and Charles M. Lovett, Professor
of Chemistry
Nucleic Acids Res., 33, 6287-6295 (2005)
The Bacillus subtilis LexA protein represses the SOS response to DNA
damage by binding as a dimer to the consensus operator sequence
5'-CGAACN4GTTCG-3'. To characterize the requirements for LexA
binding to SOS operators we determined the operator bases needed for
site-specific binding as well as the LexA amino acids required for operator
recognition. Using mobility shift assays to determine equilibrium constants for
B. subtilis LexA binding to recA operator mutants, we found that
several single base substitutions within the 14 base pair recA operator
sequence destabilized binding enough to abolish site-specific binding. Our
results show that the AT base pairs at the 3rd and 4th
positions from the 5'- end of a 7 bp half site are essential and that the
preferred binding site for a LexA dimer is 5'-CGAACATATGTTCG-3'. Binding
studies with LexA mutants, in which the solvent accessible amino acid residues
in the putative DNA binding domain were mutated, indicate that Arg-49 and His-46
are essential for binding and that Lys-53 and Ala-48 are also involved in
operator recognition. Guided by our mutational analyses as well as hydroxyl
radical footprinting studies of the dinC and recA operators we
docked a computer model of B. subtilis LexA on the preferred operator
sequence in silico. Our model suggests that binding by a LexA dimer involves
bending of the DNA helix within the internal four base pairs of the operator.
The Genetic Composition of the Bacillus subtilis
SOS System
Nora Au ’03, Elke Kuester-Schoeck, Veena Mandava
’00, Laura E. Bothwel ’02, Susan P. Canny ’02,
Karen
Chachu ’01, Sierra A. Colavito ’02, Shakierah N. Fuller ’04,
Eli S. Groban ’02, Laura A. Hensley ’02,
Theresa C. O'Brien
’02, Amish Shah ’01, Jessica T. Tierney ’02, Louise L. Tomm
’02, Thomas M. O'Gara,
Alexi I. Goranov, Alan D. Grossman, and Charles
M. Lovett, Professor of Chemistry
J. Bacteriol. 187, 7655-7666 (2005)
The SOS response in bacteria includes a global transcriptional response to
DNA damage. DNA damage is sensed by the highly conserved recombination protein
RecA, which facilitates inactivation of the transcriptional repressor LexA.
Inactivation of LexA causes induction (derepression) of genes of the
LexA-regulon, many of which are involved in DNA repair and survival after DNA
damage. To identify potential RecA-LexA regulated genes in Bacillus
subtilis, we searched the genome for putative LexA binding sites within 300
bp upstream of the start codon of all annotated open reading frames. We found
62 genes that could be regulated by putative LexA binding sites. Using mobility
shift assays, we found that LexA binds specifically to DNA in the regulatory
regions of 54 of these genes, which are organized in 34 putative operons. Using
DNA microarray analyses, we found that 33 of the genes with LexA binding sites
exhibit RecA-dependent induction by both mitomycin C and UV radiation. Among
these 33 SOS genes there are 22 distinct LexA binding sites preceding 18
putative operons. Alignment of the distinct LexA binding sites reveals an
expanded consensus sequence for the B. subtilis operator: 5'-
CGAACATATGTTCG-3'. Although the number of genes controlled by RecA and LexA in
B. subtilis is similar to that of Escherichia coli, only 8 B.
subtilis RecA-dependent SOS genes have homologous counterparts in E.
coli.
A Versatile Route to Benzocanthinones
J. Hodge Markgraf, Professor of Chemistry Emeritus, Adrian
A. Dowst ’04,
Laurel A. Hensley ’03, Charles E. Jakobsche
’04, Cindy J. Kalter (Leiden University),
Peter J. Webb ’02, and
Patrick W. Zimmerman ’03
Tetrahedron, 61, 9102-9110 (2005)
Benzocanthinone (1), a pentacyclic alkaloid, belongs to a large
family of β-carboline derivatives, which exhibit a broad range of
pharmacological activity. Compound 1 was synthesized by a new route,
which was also used to prepare five isomers of 1. The key step was a
radical-induced cyclization of N-aroyl derivatives of β-carboline and
carbazole.
Chemical Oscillations and Turing Patterns in a
Generalized Two-Variable
Model of Chemical Self-Replication
Kathleen M Beutel ’06 and Enrique
Peacock-López, Professor of Chemistry
Journal of Chemical Physics, 124, 2449061 (2006)
Chemical self-replication of oligonucleotides and helical peptides show the
so-called square root rate law. Based on this rate we extend our previous work
on ideal replicators to include the square root rate and other possible
nonlinearities, which we couple with an enzimatic sink. Although the
nonlinearity is necessary for complex dynamics, the nature of the sink is the
essential feature in the mechanism that allows temporal and spatial patterns.
We obtain exact general relations for the Poincare-Adronov-Hopf and Turing
bifurcations, and our generalized results include the Higgins, Autocatalator and
Templator models as specific cases.
Exact Solutions of the Quantum Double Square Well
Potential
Enrique Peacock-López, Professor of Chemistry
The Chemical Educator, 11, 333-344 (2006)
For a symmetrical quantum double square well potential, we find analytical
expressions satisfied by the quantized energies. Graphical or numerical
solutions of the former relations allow us to calculate normalization constants
and construct the first eight solutions of the Schrodinger equation. With these
exact solutions, we analyze quantum tunneling across a potential barrier and
compare our results with the experimental data for ammonia.
A Snapshot of PCB Levels in Hoosic River Sediments,
Crayfish and Brown Trout in the Tri-State Area
Elaine K. Denny ’04, Analia Sorribas ’06, and
David P. Richardson, Professor of Chemistry
Northeastern Geology and Environmental Science, 27, 276-294
(2005)
Levels of polychlorinated biphenyls in river bank sediments, crayfish and
brown trout were measured for samples taken from the Main and South Branches of
the Hoosic River, which rises in western Massachusetts and flows through
southwestern Vermont before emptying into the Hudson River. Sample sites were
principally in Massachusetts but included Main Branch sites in Vermont and New
York. The Hoosic is a fast flowing river, carrying sediment that is primarily
fine sand (ca. 75%) mixed with silt and clay (ca. 15%).
Sediment samples were collected at 14 recreationally-relevant sites on a
singe day (13 September 2003) to provide a snapshot of PCB levels that minimized
variations caused by river level, flow rate, and other weather/season-dependent
parameters. PCB contamination in the Hoosic originates at the site of the
former Sprague Electric Company (SEC) plant in North Adams, MA where a capped
waste dump has leaked Aroclors 1242 and 1254. Our measurements of Aroclor 1254
show that the average surface sediment PCB level downstream of the SEC is 0.1
ppm, varying from 0.020 to 0.235 ppm; subsurface sediments show the same average
concentration but vary more widely, from 0.010 to 0.628 ppm. South Branch PCB
levels, upstream of the SEC, are significantly lower (surface average: 0.025
ppm; subsurface average: 0.20 ppm) but indicate the presence of a diffuse, low
level source of PCB contamination on this section of the Hoosic. While PCB
levels measured in sediment samples appeared to vary somewhat randomly,
normalization for percentage of fine sediment clearly showed local PCB spikes in
the vicinity of the SEC and the dam in North Pownal, VT, and PCB dispersal along
the length of the Hoosic.
Crayfish contained levels of Aroclor 1254 that were significant (0.08 to
0.37 ppm dry weight; almost no Aroclor 1242 was detected) but that may signal a
decline in PCB levels compared to previous studies. Brown trout 1-2 years old
showed roughly equivalent amounts of both Aroclors, with levels ranging from 0.1
to 0.4 ppm (wet weight). Older trout (4-7 years old) showed significantly
higher levels of Aroclor 1242 relative to 1254 (2-5:1) with total PCB
contamination greater than 2 ppm, exceeding the U.S. Environmental Protection
Agency's consumption guidelines. These results do not indicate a significant
decline in PCB levels compared to earlier studies. They also imply that brown
trout bioaccumulate PCBs differently than crayfish and that local bans on
consumption of Hoosic river fish should remain in force.
Evidence for a Blue-Shifting Intramolecular Hydrogen Bond
in the Vibrational Overtone Spectrum of 1H-nonafluorobutane
Brian G. Saar ’05, Geoff P. O’Donoghue
’06, Adam H. Steeves ’02,
and John W. Thoman, Jr., Professor of
Chemistry
Chemical Physics Letters, 417, 159-163 (2006)
We demonstrate that the gauche conformation of 1H-nonafluorobutane contains
a blue-shifting intramolecular hydrogen bond by recording its fifth overtone
spectrum with cavity ringdown spectroscopy and performing electronic structure
calculations. The magnitude of the blue-shift is enhanced in the overtone
spectrum as compared to the fundamental. The energy difference between the
gauche conformer and the lowest energy zigzag conformer is calculated to be 288
cm-1 using density functional theory and determined to be 280±30 cm-1 using
temperature-dependent FTIR measurements. The -H...F- bonding
interaction in the gauche conformer leads to changes in bond lengths as compared
to the non-hydrogen bonded conformers.
COMPUTER
SCIENCE
Types for Safe Locking: Static Race Detection for
Java
Stephen Freund, Assistant Professor of Computer Science,
Martin Abadi, and Cormac Flanagan
ACM Transactions on Programming Languages and Systems, Volume
28(2), pp. 207-255 (2006)
This paper presents a static race-detection analysis for multithreaded
shared-memory programs, focusing on the Java programming language. The analysis
is based on a type system that captures many common synchronization patterns.
It supports classes with internal synchronization, classes that require
client-side synchronization, and thread-local classes. In order to demonstrate
the effectiveness of the type system, we have implemented it in a checker and
applied it to over 40,000 lines of hand-annotated Java code. We found a number
of race conditions in the standard Java libraries and other test programs. The
checker required fewer than 20 additional type annotations per 1,000 lines of
code.
This paper also describes two improvements that facilitate checking much
larger programs: an algorithm for annotation inference and a user interface that
clarifies warnings generated by the checker. These extensions have enabled us
to use the checker for identifying race conditions in large-scale software
systems with up to 500,000 lines of code.
Hybrid Types, Invariants, and Refinements for Imperative
Objects
Stephen Freund, Assistant Professor of Computer Science,
Cormac Flanagan, and Aaron Tomb
Proceedings of Workshop on Foundations and Developments of
Object-Oriented Languages, 12 pages (2006)
To control the complexity of large object-oriented systems, objects should
communicate via precisely-specified interfaces. Static type checking catches
many interface violations early in the development cycle, but decidability
limitations preclude checking all desired properties statically. In contrast,
dynamic checking supports expressive specifications but may miss errors on
execution paths that are not tested. We present a hybrid approach for checking
precise object specifications that reasons statically, where possible, but also
dynamically, when necessary. This hybrid approach supports a rich specification
language with features such as object invariants and refinement types.
Automatic Synchronization Correction
Stephen Freund, Assistant Professor of Computer Science and
Cormac Flanagan
Proceedings of Workshop on Synchronization and Concurrency in
Object-Oriented Languages, 10 pages (2005)
Multithreaded programs are notoriously prone to synchronization errors.
Much prior work has tackled the problem of detecting such errors. This paper
focuses on the subsequent problem of synchronization correction. We present a
constraint-based analysis that, given an erroneous program, automatically infers
(where possible) what additional locking operations should be inserted in order
to yield a correctly-synchronized program. For performance reasons, our
algorithm also attempts to minimize the number of additional lock acquires and
the duration for which the acquired locks are held. We present experimental
results that validate this approach on a number of standard Java library
classes.
Partitioning and Dynamic Load Balancing for the Numerical
Solution of
Partial Differential Equations
James D. Teresco, Assistant Professor of Computer Science,
Karen D. Devine, and Joseph E. Flaherty
Chapter in Numerical Solution of Partial Differential Equations on
Parallel Computers, Are Magnus Bruaset, Petter Bjørstad, Aslak
Tveito, editors, © Springer-Verlag, 55-88 (2006)
In parallel simulations, partitioning and load-balancing algorithms compute
the distribution of application data and work to processors. The effectiveness
of this distribution greatly influences the performance of a parallel
simulation. Decompositions that balance processor loads while keeping the
applications communication costs low are preferred. Although a wide variety of
partitioning and load-balancing algorithms have been developed, their
effectiveness depends on the characteristics of the application using them. In
this chapter, we review several partitioning algorithms, along with their
strengths and weaknesses for various PDE applications. We also discuss current
efforts toward improving partitioning algorithms for future applications and
architectures.
Hierarchical Partitioning and Dynamic Load Balancing for
Scientific Computation
James D. Teresco, Assistant Professor of Computer Science,
Jamal Faik, and Joseph E. Flaherty
Applied Parallel Computing, State of the Art in Scientific
Computation, Proceedings of the 7th International Workshop, PARA
2004 Workshop, J. Dongarra, K. Madsen, J. Wasniewski, editors. Vol. 3732
of Lecture Notes in Computer Science, © Springer-Verlag, pp. 911-920
(2006)
Cluster and grid computing has made hierarchical and heterogeneous
computing systems increasingly common as target environments for large-scale
scientific computation. A cluster may consist of a network of multiprocessors. A
grid computation may involve communication across slow interfaces. Modern
supercomputers are often large clusters with hierarchical network structures.
For maximum efficiency, software must adapt to the computing environment. We
focus on partitioning and dynamic load balancing, in particular on hierarchical
procedures implemented within the Zoltan Toolkit, guided by DRUM, the Dynamic
Resource Utilization Model. Here, different balancing procedures are used in
different parts of the domain. Preliminary results show benefits to using
hierarchical partitionings on hierarchical systems.
GEOSCIENCES
The Late Neoproterozoic Smalfjord Formation of the
Varanger Peninsula in
Northern Norway: A Shallow Fjord
Deposit
B. G. Baarli, Research Associate, Rebecca R. Levine
’03, and Markes E. Johnson, Professor of Geosciences
Norwegian Journal of Geology, 86, 133-150 (2006)
The Smalfjord Formation in the Varangerfjorden areas of northern Norway was
deposited as valley fill during an interglacial period of the Varangerian
(Marinoan) glaciation. The paleovalley was initially cut by glacial erosion and
braided rivers. Subsequent marine transgression due to glacial eustasy entered
through the fjord valley mouth located to the present WNW and advanced across an
irregular valley floor. As the initial transgression showed down, the shallow
fjord acted as a normal storm-dominated eustuary and was filled by a prograding
bay-head delta and flood-tidal delta prograding from opposite ends of the
paleovalley. The final stage of fjord fill was completed by tidal sandflats and
braided-river deposits. The latter was due to isostatic rebound in the
hinterland. Renewed transgression resulted in a return to marine conditions in
the succeeding Nyborg Formation, which spilled out of the paleovalley onto the
surrounding areas.
Sequestration of Carbonate Shell Material in Coastal
Dunes on the Gulf of
California (Baja California Sur,
Mexico)
Paul A. Skudder, III ’05, David H. Backus, Research
Associate, D. H. Goodwin,
and Markes E. Johnson, Professor of
Geosciences
Journal of Coastal Research, 22, 611-624 (2006)
Atmospheric and oceanographic conditions stimulate high productivity of
marine organisms in the Gulf of California that are bulk producers of calcium
carbonate. Due to prevailing winter winds, north-facing beaches receive vast
amounts of shell debris derived from offshore clam banks above the 50 m isobath.
As shells undergo mechanical abrasion, the smaller particles of carbonate
material are transferred from beaches by the wind and sequestered in coastal
dunes. This study reports on two dune fields from the midriff zone of the gulf.
Sieve analysis is used to describe the grain size and sorting characteristics of
seven samples from dunes at Cerro El Gallo near Mulegé and twelve samples
from dunes farther south near San Nicolás. Dune sediments also were
impregnated with epoxy to simulate rock samples from which thin sections were
made to determine composition and relative abundances of constituent grains.
The dunes at Cerro El Gallo are carbonate poor (5%–15 %) compared to those
near San Nicolás (26%-51%) and possible factors contributing to regional
variation are explored.
Another part of this study appraises the fecundity necessary to produce
any carbonate fraction integrated by coastal dunes from seashells. One of the
region’s more abundant clams, Megapitaria squalida, was used as a
model to estimate the number of individuals of a given size and age class
required to generate a cubic meter of pure carbonate sand. Satellite images of
the dune fields at El Gallo and San Nicolás were viewed to map surface
coverage. With input on the thickness of dune deposits and their composition,
it is possible to roughly estimate the number of mature Megapitaria equal to the
carbonate fraction of these dunes. The method may be applied to all coastal
dunes on the Gulf of California, and could be used to assess a part of the
region’s overall carbon budget heretofore unappreciated.
Rocky Shores and Development of the Pliocene-Pleistocene
Arroyo Blanco Basin on
Isla Carmen in the Gulf of California,
Mexico
James M. Eros ’04, Markes E. Johnson, Professor of
Geosciences, David H. Backus, Research Associate
Canadian Journal of Earth Sciences, 43, in press.
Arroyo Blanco Basin on Isla Carmen preserves a 157-m thick, nearly complete
record of Pliocene-Pleistocene history in the Gulf of California. Examples of
rocky-shore geomorphology occur on all margins of this trapezoidal-shaped, 3.3
km2 basin. A shoreline is developed in low relief on Miocene
andesite from the Comondú Group at the rear of the basin parallel to the
island’s long axis. Two end-walls trace normal faults that stayed active
during the life of the basin and maintained steep rocky shores. The basin is
filled 64% by calcarudite and calcarenite derived from crushed rhodolith debris.
Other facies include shell beds and stringers of andesite conglomerate that
define a 4° to 6° ramp. The ramp expanded onshore through Pliocene
time, based on a succession of overlapping range zones for 22 macrofossils
typical of Lower through Upper Pliocene strata in the Gulf of California. The
unconformity exposed 1 km inland at the rear of the basin is between Miocene
volcanics and Pleistocene cap rock at an elevation 170 m above sea level. Whole
rhodoliths encrusted on andesite pebbles occur above this unconformity.
Presumably, the older Miocene-Pliocene unconformity is buried beneath the ramp.
Four marine terraces with sea cliffs notched in Pliocene limestone occur at 68,
58, 37, and 12-m elevations. The 12-m terrace is associated regionally with the
last interglacial epoch between 120,000 and 135,000 years ago. Juxtaposition of
ramp and terrace features in the same exhumed basin support a long history of
gradual Pliocene subsidence followed by episodic Pleistocene uplift.
Rates of Lavaka Formation in Central Madagascar
Rónadh Cox, Associate Professor of Geosciences and
A.F. Michel Rakotondrazafy
Geological Society of America Abstracts with Programs, 37,
234 (2005)
Madagascar's tectonically oversteepened, deeply weathered central highlands
are eroding rapidly. The most visible manifestations of this process are
lavakas: deep, vertical-sided groundwater-sapping features that develop in the
thick saprolite and laterite of the microcontinent interior. Although widely
reported to be of recent vintage and related to human activity, there are in
fact few data on their rates of formation. The Miarinarivo area is a prime
candidate for increasing erosion rates if lavaka formation is driven by human
activity: it is only 100 km from the capital city, served by a paved main road,
and the surrounding countryside is well populated and heavily used for grazing
and cultivation. Field work in the Miarinarivo area confirms that individual
lavakas grow very rapidly: one lavaka that initiated in October 2002 had grown
by August 2004 to two big lobes, each about 50 m long, 12 m wide, and 15 m deep.
The volume excavated from this single feature was about 10,000 m3 in
22 months, but the erosion rate decreased through time, from about 1300
m3/month in the first year to about 450 m3/month in the
second (integrated across the whole year, although erosion is actually strongly
concentrated in the 5-month rainy season). However, although the lavakas in the
Miarinarivo area appear very fresh and recent, most of them are not. Of 240
lavakas in the mapping area in 2004, 227 appear on air photos taken in 1949,
which means that the lavaka increase rate in this area is only 0.08%/year, or
0.1/km2 yr-1. Old lavakas are not significantly bigger
than they were in 1949, although in many cases their headwalls remain vertical
and vegetation-free. We infer that individual lavakas tend to reach a maximum
size early on, with minimal growth thereafter. Sediment output declines
exponentially, but limited sediment output may be maintained over many decades.
The sediment comes mainly from small-scale headwall collapse, probably in the
form of fluidized flows and low-density debris flows. Present data do not allow
us to evaluate how long it takes for lavakas to become inactive, lose their
vertical walls, and relax back to bowl-shaped depressions in the landscape; but
cosmogenic isotope studies in progress will shed light on this timescale.
Is Chaos on Europa Caused by Crust-Penetrating
Impacts?
Rónadh Cox, Associate Professor of Geosciences, Lissa
C.F. Ong ’04, and M. Arakawa, Hokkaido Univ.
36th Lunar and Planetary Science Conference (2005)
Impact breaching of Europa's solid ice surface is not only possible, but
probable. Estimates of crustal thickness range from a few 10’s of km down
to a few km or even a few hundred m in places, and numerical simulations
demonstrate that an ice shell 4-7 km thick or less is likely to be breached by 1
km diameter comets impacting at average speed. In addition, the larger impact
structures Tyre, Callanish, and Mananàn (produced by bolides of about 1-2
km diameter, based on equations in Zahnle et al., have all been interpreted to
represent partial breaching of the ice crust and leakage of fluid material from
below. If 1-2 km diameter bolides split the crust, and 2 km is only the median
diameter for impactors at Jupiter, larger bolides must produce full crustal
penetration. Many chaos areas (equidimensional and sharply-bounded) may be a
hitherto unrecognized record of full-crustal penetration by bolides.
Size-Frequency Distribution of Chaos Areas and Craters
May Represent a
Production Function at Europa
Rónadh Cox, Associate Professor of Geosciences and
Lissa C.F. Ong ’04
EOS Transactions of the AGU, Joint Assembly Supplement, 87,
33A-03 (2006)
Europa’s enigmatic chaos terrain probably represents breakage of the
brittle surface ice and exposure of fluid material. Proposed explanations have
focused on endogenic mechanisms and energy sources, but all are disputed.
Crust-penetrating bolide impacts are an alternative mechanism by which chaos
terrain could be produced, and primary evidence for this hypothesis comes from
impact experiments. Additional insights come from analysis of the
size-frequency distributions of chaos areas and craters, which combined appear
to represent a unified impact production function for Europa. The impact
size-frequency distribution at Europa is predicted to match that at Ganymede and
Callisto (e.g. Schenk et al. 2004), but this has not been shown because of the
lack of large impact craters. If, however, chaos areas are the expression of
large impacts on Europa, then the impact database for Europa is dramatically
increased, permitting examination of the production function. We show that the
size-frequency distribution of chaos plus craters does indeed match production
function at Ganymede and Callisto. From the expanded impact-retention record,
we calculate an average surface age of 600 (-400/+855) Ma. This is
substantially older than previous estimates, but still young by solar system
standards, and similar to that of the Earth.
The Lavakas of Madagascar: Setting the Record
Straight
Elizabeth A. Gress ’06, Rónadh Cox. Associate
Professor of Geosciences, A.F. Michel Rakotondrazafy
Geological Society of America Abstracts with Programs, 37,
540 (2006)
Lavakas are large gullies that form in the thick laterite and saprolite of
Madagascar's deeply-weathered crystalline basement. Although little known
outside of Madagascar, they are a common geologic hazard in this developing
nation, causing the collapse of roads and the inundation of rice fields with
debris flows. Conventional wisdom states that lavakas are directly related to
human activities and to land mismanagement, but in fact, these claims are not
based on scientific data collection. The origins of lavakas and the rates at
which they grow and evolve are not yet understood, but research suggests that
lavakas are a natural element of Madagascar's Holocene landscape. The Malagasy
highlands are characterized by steep slopes, developed in saprolite up to 100 m
thick; so the landscape is inherently unstable and prone to rapid erosion.
While it is definitely true that some lavakas form due to human activities, the
non-scientific alarmist portrayal of lavakas as wholly anthropogenic is
unfounded, and damaging to both to national morale and international perception
of the Malagasy people. By careful data collection and careful reporting, we
hope to dispel some myths and increase general understanding of the fundamental
causes of lavaka formation. Part of our goal is to make our findings widely
available. We plan to provide practical guidance to infrastructure planners in
Madagascar, by meeting local leaders and presenting our technical results in
oral and report form. We also hope to provide the general public with a
balanced picture of this complicated phenomenon, by constructing
well-illustrated summaries of our results for submission to a variety of
wide-readership and popular-science publications in English and in Malagasy.
Wide dissemination of accurate information, based on scientific principles and
high-quality data analysis, but framed clearly and interestingly, is especially
important as Madagascar gains increasing international attention due to its
prominence as a biodiversity hotspot. The challenge lies in presenting a
nuanced understanding of a complicated phenomenon in which the roles of man and
nature are intimately entangled.
Seismic Control on Location of Lavakas (Midslope Gullies)
in Madagascar
Fara Christine Rasoazanamparany, Rónadh Cox,
Associate Professor of Geosciences,
Sharron J. Macklin, and A.F. Michel
Rakotondrazafy
EOS Transactions of the AGU, Joint Assembly Supplement, 87,
H43F-01 (2006)
Madagascar's central highlands are deeply weathered, with 1-2 m of laterite
overlying 10’s of meters of saprolite. These unstable materials sit at
altitudes on the order of 1000 m in recently uplifted, steep terrain
characterized by convex hills with slopes averaging 25 degrees and local
ridge-valley elevation changes of 100-500 m. In many areas, these slopes bear
numerous erosional features called lavakas, with mapped densities up to
25/km2 in some areas. Lavakas are tadpole-shaped gullies with
vertical sides and flat floors. They are wide at the headwall and taper to a
narrow, deeply incised outfall, which connects to the valley drainage. They are
not fed by overland flow, but develop by groundwater sapping and subterranean
erosion in the porous and friable saprolite beneath the baked lateritic
duracrust. The controls on lavaka formation are poorly understood. Interplay
between climate, topography, and bedrock geology is known to be important, and
human activity is also implicated. However, there are many areas with
appropriate rainfall, hillslope geometry and geology where lavakas do not form.
Likewise, lavakas form readily in some areas with little human activity, and do
not form in other areas that are heavily used. Our analysis suggests that
seismic activity may be a significant regional factor driving lavaka formation.
Using GIS analysis, we compared the locations of recent earthquakes (1347 events
with magnitudes 3.0-5.4, recorded between 1979 and 1995) with the distribution
of zones where lavakas are abundant (as mapped by Henri Besairie in 1957), and
found that they are strongly correlated. We cannot say whether individual
seismic events are responsible for specific lavakas; but the observation that
lavakas are most common in zones that are seismically active implies that
earthquakes play a significant role. Repeated mild earth-shaking events might
aid in loosening the saprolite and making it more vulnerable to lavaka-forming
processes; or individual earthquakes might initiate collapse of slopes already
weakened by groundwater sapping. More detailed work into the relationships
between individual lavakas and local seismicity is needed to determine which of
these mechanisms might be active. Our ongoing GIS analysis will quantify the
relative importance of geology, topography, and seismicity in the location of
lavaka-prone areas.
The Role of the Valley Braidplain as a Sediment Sink:
Linnédalen, Spitsbergen, Svalbard
Nora L. Matell ’06 and Rónadh Cox, Associate
Professor of Geosciences
36th International Arctic Workshop, INSTAAR (2006)
Laminated lake sediments in Linnévatnet, on Spitsbergen, provide a
high-resolution climate record of the Holocene (Svendsen and Mangerud, 1997;
Werner, 1988). Sedimentation in Linnévatnet, like other Arctic lakes,
depends on many variables, including winter snowpack, glacial ablation, and
sediment availability (Hardy, 1996). A comprehensive understanding of current
hydrology and sediment dynamics in the valley is essential to developing a
detailed understanding of past climatic history. This study provides a
detailed, if short duration, picture of the role of the Linné river
braidplain as a sediment sink. Further quantification is vital to an
understanding of sediment dynamics in the valley and sediment flux into the
lake, but will require multi-year observations that also include the early
meltwater floods. Other studies of suspended sediment flux in Arctic glacial
systems have identified areas that act as sediment sinks during mid to late
summer low flows, and sediment sources during early summer high flows (Hodgkins
et al., 2003). It is still unknown whether this occurs in Linnédalen.
However, it is clear that the valley braidplain plays a highly important role in
sediment transport between Linnébreen and Linnévatnet.
Geomorphic Inferences from Regolith Thickness, Chemical
Denudation and CRN Erosion Rates near the Glacial Limit, Boulder Creek Catchment
and Vicinity, Colorado
David P. Dethier, Professor of Geosciences and Eli D.
Lazarus ’04
Geomorphology, 75, 384-399 (2006)
Granitic regolith developed in the Boulder Creek catchment and adjacent
areas records a history of deep weathering, some of which may predate Quaternary
time. Field and well-log measurements of weathering, chemical denudation and
erosion rates derived from 10Be cosmogenic radionuclide (CRN) data
help to quantify rates of landscape change in the post-orogenic Rocky Mountains.
The density of oxidized, fractured bedrock ranges from 2.7 to about 2.2 gm
cm-3, saprolite and grus have densities between ~2.0 and 1.8 gm
cm-3, and 30 soil samples averaged 1.6 ± 0.2 gm cm-3.
Highly weathered regolith in ~540 wells averages ~3.3 m thick, mean depth to
bedrock in 1661 wells is ~7 m, and the weathered thickness exceeds 10 m in
relatively large local areas east of the late Pleistocene glacial limit.
Regolith thickness shows no simple relationship to rock type or structure, local
slope, or distance from channels. Catchments in the vicinity of the Boulder
Creek have an average CRN erosion rate of 2.2 ± 0.7 cm kyr-1 for
the past 10,000 to 40,000 years. Annual losses of cations and SiO2
vary from about 2 to 5 g m-2 over a runoff range of 10 to nearly 160
cm.
Using measured rates in simple box models shows that if a substantial
fraction of void space is created by volume expansion in the weathering rock
materials, ~7 meters of weathered rock materials could form in as little as 230
kyr. However, if density loss results mainly from chemical denudation and some
volume expansion, the same weathering profile would take >1340 kyr to form.
Erosion rates measured by CRN could be balanced by the rate of soil formation
from saprolite if the annual solute loss from soil is 2.0 g m-2 and
70% of the density decrease from saprolite to grus and soil results from strain.
Saprolite, however, forms from oxidized bedrock at a far slower rate and rates
of saprolite formation cannot balance soil and grus losses to erosion. The zone
of thick weathered regolith is likely an eroding relict landscape. The
undulating surface marked by relatively low relief and tors is not literally a
topographic surface of Eocene, Oligocene or Miocene age unless it was covered
with deposits that were removed in Pliocene or Quaternary time.
Interglacial Pumice in Whidbey Formation at Blowers
Bluff,
Central Whidbey Island, Washington
David P. Dethier, Professor of Geosciences, A.M.
Sarna-Wojcicki, and R.J. Fleck
Geological Society of America Abstracts with Programs, 37(7),
180 (2005)
A new 40Ar/39Ar age and chemical analyses of dacitic pumice from
pumice-rich alluvium at Blowers Bluff, central Whidbey Island, show that the
interglacial deposits at that site have an age of about 120 ka. Pumice is found
as thin beds, lenses as thick as 80 cm and bedded pumiceous alluvium in a 15
m-thick sequence of deposits that lies beneath two tills and middle Wisconsinan
glaciomarine deposits at Blowers Bluff. Plagioclase separated from the pumice
contained minor excess argon and gave a plateau age of 128 ± 9 ka and an
isochron age of 120 ± 50 ka. The 40Ar/39Ar age is similar to a TL age
estimate reported by Berger and Easterbrook (1993) from adjacent deposits.
These ages suggest that the pumice deposits at Blowers Bluff are part of the
Whidbey Formation, a widespread, mainly subsurface unit in the northern Puget
lowland. The glass chemistry of the pumice does not match any known source, but
Glacier Peak and Mt. Baker are likely candidates. During Whidbey Fm time, deep
troughs of the modern northern Puget Sound area must have been filled with
fluvial and lacustrine deposits, allowing volcanic-rich sediment to reach what
is now Whidbey Island. Erosion of thick glacial and interglacial deposits
occurred during ice retreat when a west-flowing lobe of Vashon ice carved what
is now Penn Cove. Fragments and local cm-thick layers of an undated pumice crop
out in latest Wisconsinan (Everson) glaciomarine deposits exposed in gravel pits
on Ebey's Prairie, 10 to 15 km WSW of Blowers Bluff. Chemistry of the pumice
suggests a Cascade source, but does not correlate with pumice chemistry from
Blowers Bluff. Balanus fragments in the glaciomarine gravel gave 14C ages
>40 ka, suggesting that they were reworked from stratigraphically and
topographically lower deposits. The undated pumice could have been reworked
from older deposits during erosion of Penn Cove and adjacent troughs or record
an eruption at about 13 ka, when glaciomarine deposits were graded to a local
relative sea level of ~70 m.
Slow Chemical Weathering of Granitic Rocks, Front Range,
Colorado
Jennifer E. Campbell ’05 and David P. Dethier,
Professor of Geosciences
Geological Society of America Abstracts with Programs, 37(7),
430 (2005)
The chemistry of weathered materials and solute export values from the
Middle Boulder Creek catchment, Colorado, allow us to measure slow weathering
processes that produced thick regolith that locally mantles the Front Range. In
areas outside the glacial limit, the weathered profile consists of 4 to 8 m of
oxidized bedrock, saprolite, and grus, capped by a thin soil. We measured the
density and chemistry of ~120 fresh and weathered granitic samples and the
chemistry of ~30 water samples collected from small drainages in alpine and
forested areas. Thin sections show that plagioclase, which comprises 15 to 35%
of fresh Boulder Creek Granodiorite and Silver Plume Granite, is the main
altered mineral. In thin section, biotite shows slight bleaching and expansion
along cleavage planes, but plagioclase is more weathered. Microcline and quartz
are little altered, suggesting the weathering sequence
plagioclase>biotite>microcline>quartz. Mass balance analyses
demonstrate that elemental loss increases up through the weathering profile as
Ca>Mg>>Na>Si>K. Solute export in surface waters demonstrates
significant losses of Ca and Mg, in addition to SiO2 and Na.
Depletion of Ca in weathering profiles and molar Ca/Na values >1 in surface
water, however, indicate loss of Ca over Na in excess of that supported by
congruent weathering of plagioclase. Decreased Ca/Na in weathering profiles may
record rapid dissolution of minor hornblende or trace phases. Excess Ca in
drainage water may reflect rapid weathering of minor amounts of calcic minerals
derived from bedrock or from dustfall. Local catchments export dissolved
cations + silica at rates from about 2 to 5 T m-2 kyr-1
over a runoff range of 10 to nearly 160 cm; average cosmogenic radionuclide
(CRN) erosion rates in the vicinity are ~2.2 cm kyr-1. Simple
modeling shows that if 70% of the void space is created by volume expansion, CRN
erosion rates could be balanced by grus + soil formation from saprolite if most
of the annual solute loss comes from the soil zone. Rates of saprolite
formation from oxidized bedrock, however, cannot balance soil and grus losses to
erosion. Thick saprolite likely reflects a relict landscape that is eroding in
the present climate. Better modeling of long-term processes requires clearer
understanding of altering minerals and solute origin in the weathering
profile.
Erosion and Burial of Granite Rocky Shores in the Recent
and Late Pleistocene of the Seychelles Islands: Physical and Biological
Perspectives
Markes E. Johnson, Professor of Geosciences and G.B.
Baarli
Journal of Coastal Research, 21, 887-899 (2005)
Modern and abandoned Pleistocene rocky shores are described for several of
the Seychelles Islands in order to examine the range of erosional features
typical of granite shores in a tropical setting and to gauge the prospects for
their preservation at unconformities in the rock record. The proportion of
sandy beaches to rocky shores is estimated for each of the various islands under
consideration, including Mahé, Praslin, Ronde, La Digue, Grande
Soœur, and Cocos. Aspects of physical geography related to the position of
reefs and the variable width of lagoons that surround and buffer the islands is
considered with respect to the regional pattern of prevailing winds and oceanic
circulation. Literature on the erosion of granite landforms is reviewed and
applied to the Seychelles Inner Islands and the Seychelles Bank on which they
sit. Outcrops of Pleistocene limestone closely associated with granite surfaces
were searched for body fossils that represent an intertidal rocky-shore biota.
Coralline red algae and vermetid gastropods are the primary components of
laminated limestone attached directly to granite surfaces as protective
bioconstructions. Cemented limestone rubble includes the body fossils of a
dozen different kinds of invertebrates also found extant on modern granite
shores in the Seychelles. Among them are gastropods that represent a range of
different life styles, as well as corals.
Relationship of Silurian Sea-Level Fluctuations to
Oceanic Episodes and Events
Markes E. Johnson, Professor of Geosciences
Geologiska Föreningens in Stockholm Förhandlingar,
128, 115-121 (2006)
Eight distinct highstands in sea level emerged from the author’s
study of the Silurian System on a continent-to-continent basis during the
1980’s and 1990’s. Some emendations are needed to accommodate other
trends recognized since that time, but the overall pattern is strong. Five
major highstands and one minor highstand fit the Lower Silurian (Llandovery and
Wenlock series). Three major highstands fit the Upper Silurian (Ludlow and
Prídolí series). Three separate episodes of glaciation correspond
to drops in sea level from the Lower Silurian but fluctuations recorded in the
Upper Silurian have no clear cause. Many oceanic events share common trends
when the relationship with sea-level fluctuations is tested against a tight
biostratigraphic framework. The Sandvika Event correlates with a sea-level drop
between the second and third highstands from the Llandovery Series. An unnamed
secundo-primo event overlaps the fall between the third and fourth highstands.
The Ireviken Event corresponds to a drop near the basal Wenlock. The Boge Event
matches a minor draw down superimposed on the fifth rise from the Sheinwoodian
Stage. The Mulde Event partly fits a drop in the Lower Homerian Stage. The
Linde Event corresponds to the low between the sixth and seventh peaks from the
Ludlow Series and the Klev Event fits the lowstand between the seventh and
eighth peaks near the Ludlow-Pridolí boundary. The Lau Event, however,
appears to adjoin the seventh highstand. No known event corresponds to the draw
down between the first and second sea-level peaks recorded in the Llandovery
Series.
Vertebrate Remains on Ancient Rocky Shores: A Review with
Report on
Hadrosaur Bones from the Upper Cretaceous of Baja California
(México)
Markes E. Johnson, Professor of Geosciences, J.
Ledesma-Vázquez, Universidad Autónoma de Baja California,
and
B.G. Baarli, Research Associate
Journal of Coastal Research, 22, 574-580 (2006)
The bones and teeth of vertebrates occur on shorelines in quantities
sufficient to provide a guide to the range of animals that live both inland and
offshore. Burial is necessary for any remains to enter the fossil record and
coastal deposits representing intertidal and shallow subtidal environments are
potential repositories of this record. A survey of 150 published reports on
rocky shores from the Cambrian to the Pleistocene reveals approximately 5% in
which vertebrate remains are listed and described. In all cases, the
vertebrates involved are marine in habit but there is no reason to suppose that
the remains of land-dwelling vertebrates should be excluded from such deposits.
The potential for dinosaur remains to be incorporated in marine coastal deposits
is appraised with particular attention to the Upper Cretaceous of Baja
California (México) and southern California (USA). Newly discovered
hadrosaur (duckbill) dinosaur bones from the Eréndira area on the Pacific
coast of Baja California (México) are described as related to a Late
Cretaceous rocky shoreline.
Sequestration of Carbonate Shell Material in Coastal
Dunes on the
Gulf of California (Baja California Sur,
Mexico)
Paul A. Skudder, III ’05, David H. Backus, Research
Associate, D. H. Goodwin,
and Markes E. Johnson, Professor of
Geosciences
Journal of Coastal Research, 22, 611-624 (2006)
Atmospheric and oceanographic conditions stimulate high productivity of
marine organisms in the Gulf of California that are bulk producers of calcium
carbonate. Due to prevailing winter winds, north-facing beaches receive vast
amounts of shell debris derived from offshore clam banks above the 50 m isobath.
As shells undergo mechanical abrasion, the smaller particles of carbonate
material are transferred from beaches by the wind and sequestered in coastal
dunes. This study reports on two dune fields from the midriff zone of the gulf.
Sieve analysis is used to describe the grain size and sorting characteristics of
seven samples from dunes at Cerro El Gallo near Mulegé and twelve samples
from dunes farther south near San Nicolás. Dune sediments also were
impregnated with epoxy to simulate rock samples from which thin sections were
made to determine composition and relative abundances of constituent grains.
The dunes at Cerro El Gallo are carbonate poor (5%–15 %) compared to those
near San Nicolás (26%-51%) and possible factors contributing to regional
variation are explored.
Another part of this study appraises the fecundity necessary to produce
any carbonate fraction integrated by coastal dunes from seashells. One of the
region’s more abundant clams, Megapitaria squalida, was used as a model to
estimate the number of individuals of a given size and age class required to
generate a cubic meter of pure carbonate sand. Satellite images of the dune
fields at El Gallo and San Nicolás were viewed to map surface coverage.
With input on the thickness of dune deposits and their composition, it is
possible to roughly estimate the number of mature Megapitaria equal to the
carbonate fraction of these dunes. The method may be applied to all coastal
dunes on the Gulf of California, and could be used to assess a part of the
region’s overall carbon budget heretofore unappreciated.
Age and Style of Emplacement of Basement Uplifts in the
Northern Appalachians
Paul Karabinos, Professor of Geosciences, Ryan P. Gordon
’05, Joseph M. Pyle, Rensselaer Polytechnic Institute
Geological Society of America, Abstracts with Programs,
37(7), 20 (2005)
Field evidence clearly shows that Middle Proterozoic basement of the
Berkshire massif in Massachusetts and Connecticut was thrust over early
Paleozoic shelf rocks of the Laurentian margin. Furthermore, it is widely
accepted that thrusting occurred during the Ordovician Taconic orogeny and that
the massif was internally shortened by numerous thrusts, even though the
evidence for these assertions is limited. Samples from well-exposed fault zones
on the west margin of the massif are spectacular mylonites with a strong,
recrystallized, planar foliation and a steep strain gradient. Sense-of-shear
indicators are mostly consistent with westward thrusting, although textures
suggest local reactivation into east-dipping normal faults. No clear evidence
exists for internal thrusting within the massif; it apparently behaved as a
rigid block during uplift. Silurian sills near the eastern margin of the massif
are distal arc-related rocks that we suggest intruded normal faults that
juxtaposed Late Proterozoic pelitic schist with basement rocks of the
massif.
Electron microprobe dating of monazite does not support a Taconic age for
thrusting. Monazite from a highly deformed quartzite exposed in the
hanging-wall of the Dry Hill fault gives an age of 392 ± 14 Ma (1s.e.,
n=16). Quartz-rich schist from a fault zone at Umpachene Falls contains
monazite grains with multiple age populations that peak at 530, 435, 380, and
290 Ma. Monazite grains in a graphitic schist from Benton Hill 200 m below a
major thrust give a weighted average age of 436 ± 8 Ma (n=21). Two
localities from Yale Farm near the western frontal thrust of the Berkshire
massif give weighted average monazite ages of 401 ± 9 Ma (n=26) and 400
± 10 (n=40). These preliminary monazite ages from well-exposed fault zones
suggest that motion on faults along the western margin of the massif occurred
during the Devonian or Silurian. So far, dating of monazite provides no
evidence that faults were active during the Ordovician Taconic orogeny.
However, one sample, collected more than 0.5 km from any major mapped fault,
does show two peaks in monazite ages at 470 and 520 Ma. This sample apparently
preserves evidence for Early Ordovician metamorphism, but more data are needed
to confirm this older age.
Silurian Subduction under the Laurentian Margin in the
New England Appalachians
Paul Karabinos, Professor of Geosciences and J.C.
Hepburn
Geological Society of America, Abstracts with Programs, 38,
32 (2006)
Igneous rocks in western New England help constrain the tectonic setting of
the Silurian Laurentian margin. In western CT, the Harrison and Newtown Gneiss
together with the Brookfield Plutonic Suite appear to record arc magmatism
during the interval 453 to 428 Ma (Sevigny and Hanson, 1993; 1995), and
Grenville age inheritance in zircon suggests contamination by Laurentian crust.
The granite at Yale Farm intruded Grenville rocks on the western edge of the
Berkshire massif in northwestern CT at approximately 430 ± 10 Ma (Zartman
et al., 1986). The granite of Beckey Quarry intruded Grenville rocks and the
Hoosac Formation along the eastern margin of the Berkshire massif in
southwestern MA at 434 ± 5 and 432 ± 2 Ma (Karabinos et al., 2003).
The geochemistry of these two informal granite units suggests that they formed
as arc magmas. The Dell Trondhjemite in northwestern MA has an arc geochemical
signature (Kim and Jacobi, 1996) and intruded the Hawley Formation at 434 ±
8 Ma (Karabinos and Aleinikoff, 1991). A felsic sill intruded the Missisquoi
Formation (MF) in Bridgewater, VT at 419 ± 1 Ma (Aleinikoff and Karabinos,
1990).
The Braintree Complex intruded the MF in Braintree, VT at 427 ± 4 Ma
and geochemistry suggests an intraplate rift setting (Ratcliffe and Aleinikoff,
2000). In southeastern VT, the Standing Pond Volcanics (SPV) and possible
feeder dikes to the SPV found in the MF preserve a back-arc basin geochemistry.
A dike in the SPV constrains this unit to be older than 421 ± 2 Ma
(Aleinikoff and Karabinos, 1990).
Thus, numerous isolated units in western New England provide evidence for a
west-dipping subduction zone under the Laurentian margin at the end of the
Ordovician Taconic orogeny through the Silurian. The limited volume of these
arc-related rocks suggests a distal setting from the arc trench and a shallow
dip of the subducting slab. This subduction zone was partly coeval with
magmatism in the Bronson Hill arc in NH and MA. At ca. 430 to 425 Ma a
transition occurred from arc magmatism to back-arc rifting that led to
sedimentation in the Connecticut Valley trough. There are two viable models for
the Bronson Hill arc. We suggest it formed above the west-dipping subduction
zone near the Laurentian margin. However, it may be a peri-Gondwanan arc that
was accreted in the Silurian (van Staal et al., 1998).
Accretion of Northern Appalachian Arc Terranes
Paul Karabinos, Professor of Geosciences
Geological Society of America, Abstracts with Programs, 38,
20 (2006)
Compilation of numerous studies shows that western New England contains
arc-related igneous rocks ranging in age from 496 to 428 Ma. Because arc
terranes provide important constraints on along-strike correlations and the
tectonic assembly of the Appalachians, it is critical to delineate separate arcs
and to determine where they formed in Iapetus. For example, recent studies show
that arc magmatism was widespread in the Appalachians and Caledonides between
480-470 Ma. Paleomagnetic and fossil evidence from Newfoundland, however,
demonstrates that coeval arcs developed near Laurentia, near Gondwana, and
within Iapetus (MacNiocaill and others, 1997); thus correlations based on age
alone are tenuous. Karabinos et al. (1998) argued that the Shelburne Falls arc
(SFA) formed on a rifted fragment of Laurentia and collided with the Laurentian
mainland during the Taconic orogeny (470-455 Ma). They suggested that the
younger Bronson Hill arc (BHA) (454-442 Ma, Tucker and Robinson, 1990) formed
after a reversal in subduction polarity above a west-dipping subduction zone
near Laurentia. In contrast, van Stall et al. (1998) correlated the BHA with
the peri-Gondwanan Popelogan-Victoria arc and suggested a Late Ordovician
collision with Laurentia. A lack of paleomagnetic and fossil data in western
New England makes it difficult to test these models, and geochemical studies
have been inconclusive. The following observations suggest, but do not prove,
that the BHA formed near Laurentia: (1) in western CT and MA arc-related rocks
(453-428 Ma) intruded Grenville basement and previously accreted SFA rocks,
indicating that a west-dipping subduction zone existed under Laurentia, (2)
volcanics rocks coeval with the SFA and BHA are separated by an unconformity in
northern New Hampshire (Moench and Aleinikoff, 2003), (3) the Connecticut Valley
trough, which separates the SFA and BHA, contains rift related volcanics that
began to form soon after arc magmatism in the BHA ceased, consistent with a
back-arc basin forming above a west-dipping subduction zone. To resolve the
tectonic significance of the BHA, future studies should search for evidence of
crustal contamination in arc-related igneous rocks and establish the provenance
of sedimentary rocks intruded by arc plutons and interbedded with arc
volcanics.
Geochronological Constraints of the Emplacement of
Basement Uplifts in the
Northern Appalachians
Paul Karabinos, Professor of Geosciences, David Morris
’05, Ryan Gordon ’05,
and Joseph Pyle, Rensselaer Polytechnic
Institute
Geological Society of America, Abstracts with Programs, 38,
63 (2006)
Middle Proterozoic basement of the Berkshire massif in MA and CT was thrust
westward over early Paleozoic shelf rocks of the Laurentian margin. Although,
it is widely accepted that displacement on the frontal thrust occurred during
the Ordovician Taconic orogeny, evidence for the age of thrusting is limited.
We used zircon SHRIMP methods to date five felsic sills previously interpreted
as syn-tectonic intrusives into Taconic thrusts. Two of these samples are from
the eastern margin of the massif and give Silurian igneous crystallization ages
of 432 ± 3 Ma (n=11) and 434 ± 5 Ma (n=8). Xenocrystic zircon cores
(950 to 1250 Ma) indicate contamination by Grenville basement. Igneous zircon
rims from three felsic sills located in the interior and western margin of the
massif yield SHRIMP ages of 997 ± 10 Ma (n=16), 1004 ± 19 Ma (n=8),
and 1003 ± 8 Ma (n=7). Cores from these zircons range from 1050 to 1230
Ma. Thus, none of the sills formed during the Ordovician Taconic orogeny.
The well-exposed frontal thrust zone on the western margin of the massif
contains spectacular mylonites with steep strain gradients over tens to hundreds
of meters. Electron microprobe dating of monazite from fault-zone samples does
not support a Taconic age for thrusting. Monazite from a highly deformed
quartzite exposed in the hanging-wall of the Dry Hill fault gives an age of 392
± 14 Ma (1s.e., n=16). Quartz-rich schist from a fault zone at Umpachene
Falls contains monazite grains with multiple age populations that peak at 530,
435, 380, and 290 Ma. Monazite grains in a graphitic schist from Benton Hill
200 m below a major thrust give a weighted average age of 436 ± 8 Ma
(n=21). Two localities from Yale Farm near the western frontal thrust of the
Berkshire massif give weighted average monazite ages of 401 ± 9 Ma (n=26)
and 400 ± 10 (n=40).
The preliminary monazite ages from frontal thrust zone suggest that motion
on faults along the western margin of the Berkshire massif occurred during the
Acadian orogeny. We found no clear evidence for internal thrusting within the
massif; it apparently behaved as a rigid block during uplift. Silurian sills
near the eastern margin of the massif are distal arc-related rocks that appear
to have intruded normal faults along the western margin of an incipient back-arc
basin that evolved into the Connecticut Valley trough.
Coccolith Chemistry as Proxy of Coccolithophorid
Productivity Response to Monsoon Cycles
Andrea Burke ’06, Alicia Arevalos ’05, Seth
Zeren ’05, P. Ziveri, N. Shimizu, and
Heather M. Stoll, Assistant
Professor of Geosciences
EOS, Transactions of the American Geophysical Union, 86(52),
OS51A-0550 (2005)
Coccolithophorid algae are important to the marine biologic carbon pump
because their coccoliths are believed to be the dominant ballast increasing the
transfer efficiency of organic carbon into the deep sea. Efforts to reconstruct
coccolithophorid production from CaCO3 accumulation are complicated
by variable dissolution, hence we use sediment traps to explore coccolith
chemistry (Sr/Ca and stable isotopes) as a proxy for coccolithophorid
production. In biogenically dominated fluxes of the Arabian Sea, coccolith Sr/Ca
covaries with primary productivity, coccolithophorid calcification, and
coccolith export to shallow 1000m traps. However in Bay of Bengal traps
lithogenic fluxes during the southwest monsoon dramatically increase export of
all coccoliths during the southwest monsoon, although Sr/Ca and productivity of
some species is highest in Northeast monsoon. In Quaternary coccoliths from the
Bay of Bengal and Arabian Sea Sr/Ca variations closely track precessional
monsoon cycles. In the Arabian Sea, strong summer monsoons drive high
productivity due to increased upwelling intensity. In contrast in the Bay of
Bengal high productivity during monsoon maxima likely reflects either shifts in
chemical weathering intensity or in groundwater nitrate release due to increased
vegetation and runoff.
Coccolith Chemistry to Track Coccolithophore
Productivity: Modern Calibrations and Coherent Responses to Precessional Monsoon
Forcing
Heather M. Stoll, Assistant Professor of Geosciences, P.
Ziveri, Andrea Burke ’06,
Susanna Theroux ’05, N. Shimizu, and
M. Conte
Geophysical Research Abstracts, 8. 10699 (2006)
Coccolithophorid CaCO3 production can account for 20-80% of
biogenic carbonate exported from the photic zone, and coccoliths are a dominant
biogenic carbonate in many deep sea sediments. A new method for picking
individual coccoliths from sediment traps and sediments for analysis using
Secondary Ion Mass Spectrometry (ion probe) allows us to make precise Sr/Ca and
Mg/Ca determinations on coccoliths from single species even in trap samples
where material is very limited. There are large biological effects in Sr/Ca
partitioning in coccoliths, which have been related to variations in
coccolithophorid productivity. In sediment traps from Bermuda, Arabian Sea, and
Bay of Bengal, we can identify Sr/Ca variations in several species, which are
consistent with inferred seasonal variations in coccolithophorid productivity in
surface waters. In the Arabian Sea, coccolith Sr/Ca ratios in Calcidiscus
leptoporus and Helicosphaera carteri are lowest during the
nonproductive intermonsoon and highest during the upwelling of southwest monsoon
and nutrient entrainment from strong winds of northeast monsoon. Sr/Ca
variations in C. leptoporus are larger, and this species also has the
greater variation in export flux between southwest monsoon and intermonsoon
seasons. At Bermuda, a 1996 fall bloom driven by passage of a warm mesoscale
feature induced large change in Sr/Ca of C. leptoporus coincident with an
increase of C. leptoporus export, but over an annual series for 2004
highest Sr/Ca ratios of C. leptoporus in the summer month match the
typical summer peak in surface standing stock of this species but did not
coincide with the highest export of C. leptoporus coccoliths. This
method allows us to examine coccolith Sr/Ca in downcore settings with much
better constraints on potential diagenetic alteration of carbonate chemistry.
Coherent coccolithophorid productivity responses to precessional variations in
monsoon intensity are tracked by coccolith Sr/Ca in the Bay of Bengal, Arabian
Sea, and Eastern Mediterranean.
Temporal Variation in Dripwater Chemistry in the Cueva
del Pindal (Asturias, NW Spain)
Heather M. Stoll, Assistant Professor of Geosciences, M.
Jimenez, and Tyler Auer ’07
CuevaTur: 1 Congreso Español Sobre Cuevas Turisticas,
1, 7 (2006)
The Pindal Cave (Asturias, NW Spain) is hosted by limestones of the
Barcaliente Formation 24 m above sea level and in close proximity (50m) to the
coastal sea cliffs. For eleven months, dripwater flow was collected in 153
discrete samples each representing integrated flow over 48 hours. Dripwater
flow rate is compared with precipitation and the major element chemistry of
dripwaters. Dripwater flow rates vary dramatically from sample to sample,
typically lagging precipitation peaks by 1-3 days. Overall dripwater flow is
highest in the wet winter season and lowest in the dry summer season.
Concentrations of Ca vary dramatically from sample to sample and are highly
positively correlated with the daily-weekly variations in dripwater flow. Mean
Ca concentrations are comparable during summer and winter months, despite lower
summer drip flow, probably because higher soil CO2 during the summer growing
season increases dissolution of host rock during infiltration, compensating for
longer Ca residence times. Sr/Ca ratios and Mg/Ca ratios correlate inversely
with dripwater flow rates, and together with Ca variations imply variable
precipitation of calcite during aquifer throughflow. The concentration of Na in
dripwaters reflects prevailing wind direction and transport of sea salt aerosols
into the cave drainage basin and correlates with the NAO index, whereas
concentrations of K are influenced by biological uptake and episodic
anthropogenic inputs.
Climate Change: The Arctic Tells Its Story
Heather M. Stoll, Assistant Professor of Geosciences
Nature, 441, 579-581 (2006)
The Arctic is one of the sensitive pressure-points for Earth’s
climate. Core information now reveals much more about the region’s role in
a long-term transition from “greenhouse” to “icehouse”
conditions. Just as a white T-shirt keeps us cooler on a hot sunny day, a
blanket of reflective snow and sea ice over the polar regions curbs the amount
of sunlight the Earth absorbs. Ice and snow cover grows in response to cooling
temperatures, and so acts as an amplifier of climate change, but the Arctic and
the Antarctic were not always frozen and barren. Over the past 55 million years
or so, the Earth has experienced a major cooling, from a greenhouse climate to
the current icehouse climate. The results of a remarkable scientific project in
the Arctic as reported in three papers in this issue2–4,
provide a detailed picture of the Arctic’s role in the long-term cooling,
and its response during oscillations of the preceding greenhouse climates.
Coccolith Chemistry Response to Nutrient
Limitation
P. Ziveri, I. Probert, and Heather M. Stoll, Assistant
Professor of Geosciences
Geophysical Research Abstracts, 8. 10697 (2006)
A main objective of the Euroclimate MERF* project is to reconstruct - the
gradients in biological productivity, expected if nutrients entered the
Mediterranean Sea from distinct sources such as rivers, and – the
variations in the productivity of species in different ecological niches
throughout the water column. The Mediterranean basin was selected since it is
characterized by monsoon cycles, which increased nutrient fluxes to the ocean
every 23,000 years. A suite of new proxy indicators derived largely from
inorganic chemistry of primary producing coccolithophores (dominant calcareous
phytoplankton group in the Mediterranean Sea), d15N and d13C of organic
compounds, and C:P ratios in sediments, are all well-suited to this work. We
will present here the first calibration from culture experiments of the
carbonate chemical signatures with respect to the influence of major nutrients.
We will discuss how the chemistry (d13C,d18O, Sr/Ca) and morphological and
physiological characteristics (cell size, growth rates, calcification rates) of
key species respond to variable nutrient levels (phosphate/nitrate) and
temperature. The selected key species constitute an important component of
modern and Quaternary sediments of the Mediterranean Sea. The culture
calibrations will form the basis for continued calibration in surface sediments,
ultimately yielding the means for improved proxy measurements of past
environments.
* Quaternary marine ecosystem response to fertilization:
Mediterranean sapropel events and implications for marine carbon uptake (MERF)
(EUROCORESEUROCLIMATE)
Phytoplankton Response to Marine Fertilization during
Sapropel Formation in the
Eastern Mediterranean Sea
L. Auliaherliaty, .P. Ziveri, S.R. Troelstra, M. Prins, and
Heather M. Stoll, Assistant Professor of Geosciences
Geophysical Research Abstracts, 8, 00693 (2006)
The eastern Mediterranean Sea is an area where occasionally sapropel
(organic-rich layers deposited under anoxic conditions) deposition took place.
The area is influenced by the monsoon system involving changes in nutrient
fluxes. Marine fertilization by aeolian and riverine input might also influence
nutrient fluxes today. Detailed knowledge of these processes is important to
understand the marine productivity cycle in this area, playing a role in
modulating CO2 exchange with the atmosphere and also sequestrating it into the
ocean as a major reservoir in the carbon cycle. Relatively little is known
about the mechanisms behind these marine productivity cycles. In our research
we use the inorganic chemistry of coccolithophores, a dominant calcareous
phytoplankton group in the Mediterranean Sea, from surface sediment samples and
gravity cores spanning several sapropel deposition events. Stable isotope and
trace element data are used to reconstruct changes in nutrient flux, marine
productivity, and oceanographic conditions. Our data will be combined with
organic chemistry and sedimentologic results from the same samples.
Furthermore, relationships obtained from culture studies will be applied to the
sediment samples. This work is part of a EUROCORES-EUROCLIMATE, Project MERF
(Quaternary Marine Ecosystem Response to Fertilization).
HISTORY
OF SCIENCE
Patterns of Co-authorship: Statistical, Philosophical,
and Sociological Implications
Donald deB. Beaver, Professor of History of Science
Proceedings of ISSI 2005, 10th International Conference of the
International Society for Scientometrics and Informetrics, Stockholm, Sweden,
July 24-28, 2005: pp. 727-730.
The vanishing single-authored paper seems to have hit a limit below which
it will strongly resist further encroachment by collaboration or teamwork. That
limit is about one paper in ten, but varies by field of science, being lower (~1
in 16) in chemistry, but higher in biology (~1 in 7). The prevalence of single
authorship also varies between experimental (lesser) and theoretical (greater)
research. The overall pattern of the growth of collaborative research now
displays the shape of a logistic curve. Teamwork (6 or more authors) continues
to grow in all fields at the expense of collaboration (5 or fewer authors), but
the two patterns remain statistically distinct. The biological sciences came
last to display the co-authorship pattern of teamwork.
From N-rays to Webometrics
Donald deB. Beaver, Professor of History of Science
Proceedings of International Workshop on Webometrics, Informetrics, and
Scientometrics & Seventh COLLNET Meeting, COLLNET 2006,
SRDI-INIST-CNRS-LORIA, Nancy, France, 10-12 May, 2006, pp. 2-3.
MATHEMATICS
Cusp Size Bounds from Surfaces in Hyperbolic
3-Manifolds
Colin Adams, Francis C. Oakley Third Century Professor of
Mathematics
with A. Colestock, J. Fowler, W.D. Gillam, E. Katerman
Transactions of the A.M.S., Vol. 358, No. 2,
727-741 (2005)
Totally Geodesic Surfaces in Hyperbolic Knot Complements
I
Colin Adams, Francis C. Oakley Third Century Professor of
Mathematics
with E. Schoenfeld
Geometriae Dedicata, Vol. 116, 723-247
(2005)
Hyperbolic Knots
Colin Adams, Francis C. Oakley Third Century Professor of
Mathematics
Ed. by W. Menasco and M. Thistlethwaite
The Handbook of Knot Theory, Elsevier, (August 2005)
The Mathematical Ethicist
Colin Adams, Francis C. Oakley Third Century Professor of
Mathematics
Mathematical Intelligencer, Vol. 27, No. 2,
24-25 (2005)
Math Talk
Colin Adams, Francis C. Oakley Third Century Professor of
Mathematics
with Lew Ludwig
Mathematical Intelligencer, Vol. 27, No. 3,
31-32 (2005)
Phone Interview
Colin Adams, Francis C. Oakley Third Century Professor of
Mathematics
Mathematical Intelligencer, Vol. 27, No. 4,
26-28 (2005)
The Theorem Blaster
Colin Adams, Francis C. Oakley Third Century Professor of
Mathematics
Mathematical Intelligencer, Vol. 28, No. 1, 17-18 (2006)
A Shrinkage Estimator for Spectral Densities
Carsten Botts, Assistant Professor of Statistics
with Michael J. Daniels
Biometrika, Vol. 93, 179-195 (2006)
A Dual Approach to Triangle Sequences: A Multidimensional
Continued Fraction Algorithm
Thomas Garrity, Associate Professor of Mathematics
with S. Assaf, L. Chen, T. Cheslack-Postava ’00, B.
Cooper ’01, A. Diesl, M. Lepinski and A. Schuyler
Integer: The Electronic Journal of Combinatorial Number Theory,
5 (2005)
A dual approach to defining the triangle sequence (a type of
multidimensional continued fraction algorithm, initially developed in [Garrity1]
for a pair of real numbers is presented, providing a new, clean geometric
interpretation of the triangle sequence. We give a new criterion for when a
triangle sequence uniquely describes a pair of numbers and give the first
explicit examples of triangle sequences that do not uniquely describe a pair of
reals.
Finally, this dual approach yields that the triangle sequence is
topologically strongly mixing, meaning in particular that it is topologically
ergodic.
Protecting Information: From Classical Error Correction
to Quantum Cryptography
Susan Loepp, Associate Professor of Mathematics with William
Wootters
Cambridge University Press, (2006)
Real Analysis
Frank Morgan, Webster Atwell Class of 1921 Professor of
Mathematics
American Mathematical Society, (2005)
Based on a one-semester core real analysis course at Williams.
Regularity of Area-Minimizing Surfaces in 3D Polytopes
and of Invariant Surfaces in Rn
Frank Morgan, Webster Atwell Class of 1921 Professor of
Mathematics
J. Geom. Anal., preprint at arvix.org, 321-341 (2005)
In the surface of a convex polytope P3 in R4,
an area-minimizing surface avoids the vertices of P and crosses the edges
orthogonally. In a smooth Riemannian manifold M with a group of isometries G, an
area-minimizing G-invariant oriented hypersurface is smooth (except for a very
small singular set in high dimensions). Already in 3D, area-minimizing
G-invariant unoriented surfaces can have certain singularities, such as
three orthogonal sheets meeting at a point. We also discuss flat chains modulo
μ and soap films.
Real Analysis and Applications (Including Fourier Series
and the Calculus of Variations
Frank Morgan, Webster Atwell Class of 1921 Professor of
Mathematics
American Mathematical Society, (2005)
Streamlined, complete theory, plus applications in Fourier series and the
calculus of variations, including physics (least action and Lagrange’s
equations), economics (optimal production and maximal utility), Riemannian
geometry, and general relativity.
Clusters with Multiplicities in R2
Frank Morgan, Webster Atwell Class of 1921 Professor of
Mathematics
Pacific J. of Math, 221, 123-146 (2005)
Perimeter-minimizing planar double soap bubbles in which regions are
allowed to overlap with multiplicities meet in fours, fives, and sixes as well
as threes. We further provide certain generalizations to immiscible fluids and
higher dimensions, and an associated theory of calibrations. We work in the
category of flat chains with coefficients in a normed group.
Teaching Tips
Frank Morgan, Webster Atwell Class of 1921 Professor of
Mathematics, with Tom Garrity
Amer. Math. Soc., (2005)
Easy ways to be a better teacher.
Hexagonal Surfaces of Kapouleas
Frank Morgan, Webster Atwell Class of 1921 Professor of
Mathematics
Pacific J. of Math, 220, 379-387 (2005)
For the ‘hexagonal’ norm on R3, for which the
isoperimetric shape is a hexagonal prism rather than a round ball, we give
analogs of the compact immersed constant-mean-curvature surfaces of
Kapouleas.
Manifolds with Density
Frank Morgan, Webster Atwell Class of 1921 Professor of
Mathematics
Notices Amer. Math. Soc., 52, 853-858 (2005)
We discuss the category of Riemannian manifolds with density and present
easy generalizations of the volume estimate of Heinze and Karcher and thence of
the isoperimetric inequality of Levy and Gromov.
Geometric Measure Theory and the Proof of the Double
Bubble Conjecture
Frank Morgan, Webster Atwell Class of 1921 Professor of
Mathematics, with Manuel Ritoré, David Hoffman, Editor
Amer. Math. Soc., (2005)
Global Theory of Minimal Surfaces (Proc. Clay Inst., 2001 Summer
School, MSRI)
Notes by Ritoré based on Morgan’s course at MSRI.
Class Groups of Imaginary Function Fields: The Inert
Case
Allison Pacelli, Assistant Professor of Mathematics, with
Yoonjin Lee
Proceedings of the American Math Society, 133, 2883-2889
(2005)
The Prime at Infinity and the Rank of the Class Group of
Global Function Fields
Allison Pacelli, Assistant Professor of Mathematics
Journal of Number Theory, 116, 311-323 (2006)
Weakly Mixing and Doubly Ergodic
Infinite Measure-Preserving Rd Actions
Cesar Silva, Professor of Mathematics, with S. Iams
‘04, B. Katz ‘03, B. Street, and K. Wickelgren
Colloq. Math. 103, 247-264 (2005)
Abstract: We study weak mixing and double ergodicity for nonsingular
actions of locally compact Polish abelian groups. We show that if T is a
nonsingular action of G, T is weakly mixing if and only if for all co-compact
subgroups A of G the action of T restricted to A is weakly mixing. We show that
a doubly ergodic nonsingular action is weakly mixing and construct an infinite
measure-preserving flow that is weakly mixing but not doubly ergodic. We also
construct an infinite measure-preserving flow whose Cartesian square is
ergodic.
The Statistical Distribution of the Zeros Random
Paraorthogonal
Polynomials on the Unit Circle
Mihai Stoiciu, Assistant Professor of Mathematics
Journal of Approximation Theory, 139, 29-64 (2006)
In this paper we consider random paraorthogonal polynomials on the unit
circle defined by independent identically distributed random Verblusky
coefficients. The zeros of these polynomials are random points on the unit
circle. We prove that the local statistical distribution of these zeros is
Poisson. This means that there is no local correlation between the zeros of the
considered random paraorthogonal polynomials.
PHYSICS
Quantifying Optimal Accuracy of Local Primary Sequence
Bioinformatics Methods
Daniel P. Aalberts, Associate Professor of Physics, Eric G.
Daub ’04 and Jesse W. Dill ’04
Bioinformatics, 21, 3347 (2005)
Traditional bioinformatics methods scan primary sequences for local
patterns. It is important to assess how accurate local primary sequence methods
can be. We study the problem of donor pre-mRNA splice site recognition, where
the sequence overlaps between real and decoy data sets can be quantified,
exposing the intrinsic limitations of the performance of local primary sequence
methods. We assess the accuracy of primary sequence methods generally by
studying how they scale with dataset size and demonstrate that our new Primary
Sequence Ranking methods have superior performance.
Sodium Bose-Einstein Condensates in an Optical
Lattice
Kevin M. Jones, The William Edward McElfresh Professor of
Physics, and colleagues at MIT and NIST
Physical Review A, 72, 043604 (2005)
The phase transition from a superfluid to a Mott insulator has been
observed in a 23Na Bose-Einstein condensate. A dye laser detuned
≈5 nm red of the Na 3S—>3P1/2 transition was
used to form the three-dimensional optical lattice. The heating effects of the
small detuning as well as the three-body decay processes constrained the time
scale of the experiment. Certain lattice detunings were found to induce a large
loss of atoms. These loss features were shown to be due to photoassociation of
atoms to vibrational levels in the Na2
(1)3∑g+ state.
Sub-Natural-Linewidth Quantum Interference Features
Observed in
Photoassociation of a Thermal Gas
Kevin M. Jones, The William Edward McElfresh Professor of
Physics, and colleagues at NIST
Physical Review A, 72, 041801 (2005) (Rapid
Communications)
By driving photoassociation transitions, we form electronically excited
molecules (Na2*) from ultracold (50—300 µK) Na
atoms. Using a second laser to drive transitions from the excited state to a
level in the molecular ground state, we are able to split the photoassociation
line and observe features with a width smaller than the natural linewidth of the
excited molecular state. The quantum interference which gives rise to this
effect is analogous to that which leads to electromagnetically induced
transparency in three-level atomic -systems, but here one of the ground
states is a pair of free atoms while the other is a bound molecule. The
linewidth is limited primarily by the finite temperature of the atoms.
Ultracold Photoassociation Spectroscopy: Long-range
Molecules and Atomic Scattering
Kevin M. Jones, The William Edward McElfresh Professor of
Physics, and colleagues at NIST
Reviews of Modern Physics, 78, 483 (2006)
Photoassociation is the process in which two colliding atoms absorb a
photon to form an excited molecule. The development of laser-cooling techniques
for producing gases at ultracold 1mK temperatures allows photoassociation
spectroscopy to be performed with very high spectral resolution. Of particular
interest is the investigation of molecular states whose properties can be
related, with high precision, to the properties of their constituent atoms with
the ‘complications’ of chemical binding accounted for by a few
parameters. These include bound long-range or purely long-range vibrational
states in which two atoms spend most or all of their time at large internuclear
separations. Low-energy atomic scattering states also share this
characteristic. Photoassociation techniques have made important contributions
to the study of all of these. This review describes what is special about
photoassociation spectroscopy at ultracold temperatures, how it is performed,
and a sampling of results including the determination of scattering lengths,
their control via optical Feshbach resonances, precision determinations of
atomic lifetimes from molecular spectra, limits on photoassociation rates in a
Bose-Einstein condensate, and briefly, production of cold molecules.
Discussions are illustrated with examples on alkali-metal atoms as well as other
species. Progress in the field is already past the point where this review can
be exhaustive, but an introduction is provided on the capabilities of
photoassociation spectroscopy and the techniques presently in use.
All-optical Generation and Photoassociative Probing of
Sodium Bose-Einstein Condensates
Kevin M. Jones, The William Edward McElfresh Professor of
Physics, and colleagues at NIST
New Journal of Physics, 8, 64 (2006) (IOP
Select)
We demonstrate an all-optical technique to evaporatively produce sodium
Bose-Einstein condensates (BEC). We use a crossed-dipole trap formed from light
near 1 µm, and a simple ramp of the intensity to force evaporation. In
addition, we introduce photoassociation as diagnostic of the trap loading
process, and show that it can be used to detect the onset of BEC. Finally, we
demonstrate the straightforward production of multiple traps with condensates
using this technique, and that some control over the spinor state of the BEC is
achieved by positioning the trap as well.
Nonlinear Ring Formation via Self-Phase Modulation in Hot
Atomic Vapor
Colin F. McCormick ’95, Kevin M. Jones, The William
Edward McElfresh Professor of Physics,
and others (presented by
McCormick)
Proceedings of CLEO/QUELS 2006, May 21-26 (2006)
We have observed high-contrast nonlinear optical ring formation in hot
atomic vapor. The standard Kerr model fails to predict important qualitative
features of these optical patterns, but a Doppler-broadened two-level model is
extremely successful.
EIT Enhancement of 4-Wave Mixing for Correlated Photon
Generation
Colin F. McCormick’95, Kevin M. Jones, The William
Edward McElfresh Professor of Physics,
and others (presented by V.
Boyer)
Proceedings of CLEO/QUELS 2006, May 21-26 (2006)
We report our progress towards the realization of a tunable and narrow-band
source of correlated photons for coherent manipulation of cold atoms, using a
combination of four-wave mixing and electromagnetically induced
transparency.
A Frequency Stabilization Method for Diode Lasers
Utilizing Low-field Faraday Polarimetry
J.A. Kerckhoff ’05, C.D. Bruzewicz ’05, R. Uhl,
and P.K. Majumder, Associate Professor of Physics
Rev. Sci. Instrum., 76, 093108 (2005)
We present a method of diode laser frequency stabilization based on the
Faraday rotation of linearly polarized light passing through an atomic sample in
the presence of a very modest 1 mT magnetic field. Near the zero crossing of
this spectroscopic feature, an optical system capable of very precise
polarimetry detects and corrects for very small frequency fluctuations via a
feedback system, which keeps the rotation signal at zero. In our application,
we have demonstrated robust frequency stabilization over time scales from 10 ms
to 1 h at the 1 MHz level or below. We utilize this technique to lock our laser
to a “forbidden” M1/E2 transition in thallium at 1283 nm, for which
saturated absorption techniques are not straightforward. This technique has
broad applicability to spectroscopy of various atomic systems as we also
demonstrate using a Rb cell and a780 nm diode laser.
General Issues Connecting Flavor Symmetry and
Supersymmetry
Ersen Bilgin ’06, Brian Patt, David Tucker-Smith,
Assistant Professor of Physics, and Frank Wilczek
Phys. Lett. B, 634, 69-73 (2006)
We motivate and construct supersymmetric theories with continuous flavor
symmetry, under which the electroweak Higgs doublets transform non-trivially.
Flavor symmetry is spontaneously broken at a large mass scale in a sector of
gauge-singlet fields; the light Higgs multiplets naturally emerge as special
linear combinations that avoid acquiring the generic large mass. Couplings of
the light Higgs doublets to light moduli field from the singlet sector could
lead to important effects in the phenomenology of the Higgs sector at the
LHC.
Little Higgs Theories
Martin Schmaltz and David Tucker-Smith, Assistant Professor
of Physics
Ann. Rev. Nucl. Part. Sci. 55, 229 (2005)
Recently there has been renewed interest in the possibility that the Higgs
particle of the Standard Model is a pseudo-Nambu-goldstone boson. This
development was spurred by the observation that if certain global symmetries are
broken only by the interplay between two or more coupling constants, then the
Higgs mass-squared is free from quadratic divergences at one loop. This
“collective symmetry” breaking is the essential ingredient in little
Higgs theories, which are weakly coupled extensions of the Standard Model with
little or no fine tuning, describing physics up to an energy scale ~ 10 TeV.
Here we give a pedagogical introduction to little Higgs theories. We review
their structure and phenomenology, focusing mainly on the SU(3) theory, the
Minimal Moose, and the Littlest Higgs as concrete examples.
A Minimally Fine-tuned Supersymmetric Standard
Model
Z. Chacko, Yasunori Nomura and David Tucker-Smith, Assistant
Professor of Physics
Nucl. Phys. B, 725, 207-250 (2005)
We construct supersymmetric theories in which the correct scale for
electroweak symmetry breaking is obtained without significant fine-tuning. We
calculate the fine-tuning parameter for these theories to be at the 20% level,
which is significantly better than in conventional supersymmetry breaking
scenarios. Supersymmetry breaking occurs at a low scale of order 100 TeV, and
is transmitted to the supersymmetric standard-model sector through
standard-model gauge interactions. The Higgs sector contains two Higgs doublets
and a singlet field, with a superpotential that takes the most general form
allowed by gauge invariance. An explicit model is constructed in 5D warped
space with supersymmetry broken on the infrared brane. We perform a detailed
analysis of electroweak symmetry breaking for this model, and demonstrate that
the fine-tuning is in fact reduced. A new candidate for dark matter is also
proposed which arises from the extended Higgs sector of the model. Finally, we
discuss a purely 4D theory which may also significantly reduce
fine-tuning.
Quantum Measurement and Finite Geometry
William K. Wootters, Barclay Jermain Professor of Natural
Philosophy
Foundations of Physics, (online 8 Feb. 2006)
A complete set of mutually unbiased bases for a Hilbert space of dimension
N is analogous in some respects to a certain finite geometric structure,
namely, an affine plane. Another kind of quantum measurement, known as a
symmetric informationally complete positive-operator-valued measure, is,
remarkably, also analogous to an affine plane, but with the roles of points and
lines interchanged. In this paper I present these analogies and ask whether
they shed any light on the existence or non-existence of such symmetric quantum
measurements for a general quantum system with a finite-dimensional state
space.
Distinguishing Unentangled States with an Unentangled
Measurement
William K. Wootters, Barclay Jermain Professor of Natural
Philosophy
International Journal of Quantum Information, 4, 219-232
(2006)
In a 1991 paper, Asher Peres and the author theoretically analyzed a set of
unentangled bipartite quantum states that could apparently be distinguished
better by a global measurement than by any sequence of local measurements on the
individual subsystems. The present paper returns to the same example, and shows
that the best result so far achieved can alternatively be attained by a
measurement that, while still global, is “unentangled” in the sense
that the operator associated with each measurement outcome is a tensor
product.
Protecting Information: From Classical Error Correction
to Quantum Cryptography
Susan Loepp and William K. Wootters, Barclay Jermain
Professor of Natural Philosophy
Cambridge University Press (2006)
PSYCHOLOGY
The Pathway from Child Personality to Adult Adjustment:
The Road Is Not Straight
Phebe Cramer, Professor of Psychology and Allison
Tracy
Journal of Research in Personality, 11, 369 –
394 (2005)
In a prospective longitudinal study of 62 individuals from the Berkeley
Guidance Study of the Institute of Human Development, we examined the pathway
from early childhood personality to early adult adjustment and maladjustment.
The results from a path analysis indicated that personality change between
childhood and adulthood, influenced by the use of defense mechanisms, was the
strongest predictor of adult adjustment. Increased Outgoingness, related to the
use of the defense of projection, predicted better psychological health, less
depression, but more anxiety. Increased Self-confidence, related to the use of
the defense of identification, predicted better psychological health and less
depression, but was not related to anxiety. A theoretical explanation of these
relations is provided.
Protecting the Self: Defense Mechanisms in
Action
Phebe Cramer, Professor of Psychology
New York: Guilford Press (2006)
Integrating theory, research, and practical applications, this book
provides a comprehensive examination of defense mechanisms and their role in
both normal development and psychopathology. It describes how children and
adults mobilize specific kinds of defenses to maintain their psychological
equilibrium and preserve self-esteem, particularly in situations of trauma or
stress. The impact of age, gender, personality differences, and psychotherapy
are discussed.
The Narrative Worlds of What Is and What If
Susan Engel, Senior Lecturer in Psychology
Cognitive Development, 20, 514-525 (2005)
This paper advances the hypothesis that young children use narrative play
and stories to construct two types of fiction, the worlds of
what is and
what if. Heinz Werner's
conceptualization of children's spheres of reality, in which actions, symbols,
and events are constructed in particular ways, is used as a theoretical
framework for understanding children's play and stories. Drawing on examples of
children's spontaneous pretend play and story telling, the paper argues that,
beginning in their second year, children use pretend play to differentiate the
worlds of everyday-lived reality from an alternative pretend sphere; the world
of as if. By their third year, children
engage in play that hangs on a narrative framework. Such pretend play offers
children further options: the fictional world of plausible make believe which
simulates everyday life, what is, and
the fictional world of more fantastic possibilities,
what if. While the child's use of a
narrative framework in her pretend play expands her range of psychological
worlds, the developmental shift to purely verbal stories, sometimes during the
child's third year, significantly adds to her ability to explore such worlds. An
examination of the language young children use to accompany their narrative play
and to tell stories demonstrates the ways in which children exploit the
narrative form to contrast, compare, and traverse the constructed worlds of
what is and
what if.
Real Kids: Creating Meaning in Every Day Life
Susan Engel, Senior Lecturer in Psychology
Cambridge, MA: Harvard University Press (2005)
Decades of work in psychology labs have vastly enhanced our knowledge about
how children perceive, think, and reason. But it has also encouraged a distorted
view of children, argues psychologist Susan Engel in this book--a view that has
affected every parent who has tried to debate with a six-year-old. By focusing
on the thinking processes prized by adults, too many expert opinions have
rendered children as little adults. What has been lost is what is truly unique
and mysterious--the childlike quality of a child's mind. Engel draws on keen
observations and descriptive research to take us into the nearly forgotten,
untidy, phantasmagorical world of children's inner lives. She reminds us that
children fuse thought and emotion, play and reality; they swing wildly between
different ways of interpreting and acting in the world. But just as a gawky
child may grow into a beauty, illogical and sometimes maddening childishness can
foreshadow great adult ability. Engel argues that the scientist in a crib view
encourages parents and teachers to expect more logical reasoning and emotional
self-control from children than they possess. She provides a concise and
valuable overview of what modern developmental psychologists have learned about
children's developing powers of perception and capacity for reasoning, but also
suggests new ways of studying children that better capture the truth about their
young minds.
Therapeutic Alliances in Couple and Family Therapy: An
Empirically Informed
Guide to Practice
Myrna L. Friedlander, Valentín Escudero, and Laurie
Heatherington, Professor of Psychology
Washington, DC: American Psychological Association (2006)
The book demonstrates the crucial importance of healthy working
relationships with clients in couple and family therapy. The authors’
conceptual model (System for Observing Family Therapy Alliances, or SOFTA)
integrates theory, research, and practice related to the alliance in couple and
family therapy. The authors demonstrate how to gather evidence about working
alliances by tracking specific positive and negative behaviors in therapy
sessions, including clients' as well as therapists' behavioral contributions to
the alliance.
System for Observing Family Therapy Alliances: A Tool for
Research and Practice
Myrna L. Friedlander, Valentín Escudero, Adam O.
Horvath, Laurie Heatherington, Professor of Psychology,
Andrés Cabero,
and Matthew P. Martens
Journal of Counseling Psychology, 53, 214-224 (2006)
To advance research and inform practice, the authors developed an
observational rating system of client behavior reflecting strong and weak
therapeutic alliances in couple and family therapy. The System for Observing
Family Therapy Alliances (SOFTA), in both English and Spanish, has 2 dimensions
that are common across therapy modalities (“emotional connection to the
therapist” and “engagement in the therapeutic process”) and 2
dimensions that reflect the uniqueness of conjoint treatment (“safety
within the therapeutic system” and “shared sense of purpose within
the family”). Psychometric support is provided by 5 reliability studies,
an exploratory factor analysis with data from 120 diverse English- and
Spanish-speaking couples and families, and meaningful associations with various
process and outcome indices. Recommendations are made for using the SOFTA in
research, training, and (self-)supervision.
Pretend Play and Theory of Mind
Robert D. Kavanaugh, Professor of Psychology
Child Psychology: A Handbook of Contemporary Issues, 153-166, L.
Balter & C.S. Tamis-LeMonda (Eds.) NY: Psychology Press (2006)
This chapter discusses the relationship between children’s
understanding of the thoughts and feelings of others and their linguistic and
imaginative skills.
Pretend Play
Robert D. Kavanaugh, Professor of Psychology
Handbook of Research on the Education of Young Children, 269-278, B.
Spodek & O. N. Saracho (Eds.), Mahwah, NJ: Erlbaum (2006)
This chapter discusses the role of pretend play in the development of
children’s literacy abilities and adult’s interest and involvement
in fiction and the arts.
The Present Values of Delayed Rewards Are Approximately
Additive
Kris N. Kirby, Professor of Psychology
Behavioural Processes, 72, 273-282 (2006)
In two experiments, human subjects were asked to estimate their present
values of single delayed rewards and their present values of temporal sequences
of three rewards. Present values were solicited by asking subjects to indicate
an amount of money v for which they would be indifferent between
receiving v at the end of the session and receiving the delayed
reward(s). A procedure was used for which responding the true value of v
was the optimal strategy, and the actual payoff that each subject received was
determined by one randomly selected trial. In Experiment 1 (n = 29) each
delayed reward was $9.90 in cash. In Experiment 2 (n = 19) the delayed
rewards were dated $15 gift certificates to a local restaurant. In both
experiments, the present values of the sequences were approximately equal to the
sums of the present values of their component rewards. The presence of outliers
suggests that a few subjects may have valued sequences less than the sums of
their single rewards. Effects of a preference for uniform sequences, if any,
were too small to be detected. Discounting of sequences was well-fit by a
parallel hyperbolic discounting equation, consistent with Mazur’s (1986)
results using multiple reinforcers.
Likeable vs. Popular: Distinct Implications for
Adolescent Adjustment
Marlene J. Sandstrom, Associate Professor of Psychology
& A. H. N. Cillessen
International Journal of Behavioral Development, 30,4
(2006)
In the current study, 466 children completed a peer nomination survey
assessing both perceived and sociometric popularity at the end of
the 5th grade. Measures of behavior problems were assessed through a composite
of peer-, teacher-, and self- reports at the end of the 8th grade. Examination
of the unique concurrent associations of each popularity type with peer
nominated social characteristics in 5th grade demonstrated that
sociometric popularity was positively associated with prosocial behavior and
inclusive behavior, while perceived popularity was positively associated
with overt and relational aggression. In addition to emerging as distinct
conceptual constructs, these two dimensions of popularity also demonstrated
unique associations with adjustment over time. Sociometric popularity in the 5th
grade was associated with lower levels of externalizing behavior problems 3
years later, while perceived popularity was associated with higher levels of
these problems over time. Interestingly, high levels of perceived popularity in
the 5th grade were associated with less internalizing symptoms over time for
boys, while high levels of sociometric popularity were associated with less
internalizing symptoms over time for girls.
Castration Impairs Spatial Memory Retention but
not
Spatial Learning: Reversal by Testosterone
Noah J. Sandstrom, Assistant Professor of Psychology, J. H.
Kim ’05, & M. A. Wasserman ’04
Hormones & Behavior, 50, 18-26 (2006)
Gonadal hormones have been shown to modulate memory retention in female
rats. The current experiments examine the role of testicular hormones in
modulating the performance of male rats on two spatial water maze tasks. In the
first study, castrated and intact rats were trained on the visible platform and
hidden platform versions of the Morris water maze task. Castration did not
affect performance on either version of this reference memory task with
castrated and intact rats demonstrating similar performance both during
acquisition and on post-training probe trials. In the second experiment,
castrated and intact rats were tested on a delayed-matching-to-place version of
the water maze. Rats received a series of trial pairs in the maze with a hidden
platform located in the same pool location on the exposure and retention trials
of each pair; between pairs of trials, however, the platform was repositioned to
a novel pool location. The interval between trials was either 10- or 60-min and
memory retention, taken as the difference between the pathlengths on the
exposure and retention trials, declined as the interval increased. Relative to
intact males, castrated males demonstrated impaired working memory retention at
60-min but not at 10-min retention intervals. This interval-dependent impairment
in working memory retention was reversed by physiologic levels of testosterone
replacement. These findings indicate that castration does not significantly
affect acquisition or probe trial performance on a classic reference memory task
but does impair spatial working memory retention, an effect that is reversed by
exogenous testosterone.
“Don’t Tell Me, I Don’t Want To
Know”: Understanding People’s Reluctance to Obtain Medical
Diagnostic Information
E. C. Dawson, Kenneth Savitsky, Associate Professor of
Psychology, & D. Dunning
Journal of Applied Social Psychology, 36, 751-768
(2006)
Prominent theories of health-protective behavior predict increasing
information seeking as a function of increasing disease severity, yet diagnostic
screens for serious disease are notoriously underutilized. We suggest that in
addition to severity, disease treatability impacts people’s willingness to
submit to medical tests. In two studies, participants were relatively likely to
seek a diagnostic test for a disease they believed to be serious and treatable
(Study 1) and to avoid a test for a disease they believed to be serious but
untreatable (Study 2). Implications for health-behavior models and persuasive
health communication are discussed.
The Unpacking Effect in Allocations of Responsibility for
Group Tasks
Kenneth Savitsky, Associate Professor of Psychology, L.D.
Van Boven, N. Epley, & W.M. Wight ’00
Journal of Experimental Social Psychology, 41, 447-457
(2005)
Individuals tend to overestimate their relative contributions to
collaborative endeavors. Thus, the sum of group members’ estimates of the
percentage they each contributed to a joint task typically exceeds the logically
allowable 100%. We suggest that this tendency stems partly from
individuals’ inclination to regard their fellow group members collectively
rather than individually, and that leading people to think about their group
members as individuals should therefore reduce the perceived relative magnitude
of their own contributions. Consistent with this account, four experiments
demonstrate that individuals’ tendency to claim more than their fair share
of the credit for a group task is attenuated when they “unpack”
their collaborators, conceptualizing them as separate individuals, rather than
as “the rest of the group.”
A Taxometric Investigation of Unipolar Depression in a
Large Community Sample
Ari Solomon, Assistant Professor of Psychology, J. Ruscio,
J. R. Seeley, & , P. M. Lewinsohn
Psychological Medicine, 36, 973-985 (2006)
Background. The question of whether
unipolar clinical depression differs categorically from limited depressive
complaints has important implications for the disorder's assessment, treatment
and research. This crucial issue has proven difficult to resolve, in part
because many studies to date have relied on self-report measures or on
clinically homogeneous samples. We therefore applied Meehl's taxometric method
to a large, clinically heterogeneous sample, and examined the latent structure
of depressive episodes using both self-report and structured clinical interview
data. Method. Data were derived from the
Oregon Adolescent Depression Project, a large longitudinal community study. All
analyses involved more than 1400 participants. MAXEIG (MAXimum EIGenvalue) and
base rate estimation were performed separately for Beck Depression Inventory
(BDI) items and for DSM-IV-based major depressive episode (MDE) symptoms.
Results. MAXEIG analyses of the BDI and
MDE indicator sets appeared to converge on a taxonic structure for unipolar
depression. Base rate estimates overall implied a latent depressive episode
class that occurs more frequently than diagnosable MDEs but less frequently than
persistent depressed or anhedonic mood.
Conclusions. These findings provide
tentative support for a categorical conceptualization and make it very clear
that the continuity controversy regarding unipolar depression has not yet been
decided in favor of dimensionality. To reconcile the conflicting reports to
date, several data analytic and sampling issues need to be explored
systematically
Evidence for Dissociable Neural Mechanisms Underlying
Inference Generation in
Familiar and Less-Familiar Scenarios
Brian A. Sundermeier, Visiting Assistant Professor of
Psychology, S. M. Virtue, C. J. Marsolek, & P. van den Broek
Brian and Language, 95, 402-413 (2005)
In this study, we investigated whether the left and right hemispheres are
differentially involved in causal inference generation. Participants read short
inference-promoting texts that described either familiar or less-familiar
scenarios. After each text, they performed a lexical decision on a letter string
(which sometimes constituted an inference-related word) presented directly to
the left or right hemisphere. Response-time results indicated that hemisphere of
direct presentation interacted with type of inference scenario. When test
stimuli were presented directly to the left hemisphere, lexical decisions were
facilitated following familiar but not following less-familiar inference
scenarios, whereas when test stimuli were presented directly to the right
hemisphere, facilitation was observed in both familiar and less-familiar
conditions. Thus, inferences may be generated in different ways depending on
which of two dissociable neural subsystems underlies the activation of
background information.
Procedural Interference in Perceptual Classification:
Implicit Learning or
Cognitive Complexity?
R. M. Nosofsky, R. D. Stanton, & Safa R. Zaki, Associate
Professor of Psychology
Memory & Cognition, 33, 1256-1271 (2005)
Researchers have argued that an implicit procedural-learning system
underlies performance for information integration category structures, whereas a
separate explicit system underlies performance for rule-based categories. One
source of evidence is a dissociation in which procedural interference harms
performance in information integration structures, but not in rule-based ones.
The present research provides evidence that some form of overall difficulty or
category complexity lies at the root of the dissociation. The authors report
studies in which procedural interference is observed for even simple rule-based
structures under more sensitive testing conditions. Furthermore, the magnitude
of the interference is large when the nature of the rule is made more complex.
By contrast, the magnitude of interference is greatly reduced for an information
integration structure that is cognitively simple. These results challenge the
view that a procedural-learning system mediates performance on information
integration categories, but not on rule-based ones.
Behavioral Effects of Toluene in Rats Selectively Bred
for Infantile Vocalization Rate
Nicholas A. Bamat ’04, Susan A. Brunelli, Michelle M.
Kron ’04, Andrew R. Schulte ’03, and
Betty Zimmerberg, Professor
of Psychology
Neurotoxicology and Teratology, 27, 883-890 (2005)
Glue sniffing is epidemic among children living in poverty in Latin
America. Previous research has shown that abused inhalants such as toluene share
pharmacological properties with anxiolytic drugs, and that personality factors
such as degree of anxiety have been proposed to modulate the effects of these
drugs. To study this interaction in an animal model, rats selectively bred for
high (High) or low (Low) rates of distress calls after maternal separation
(ultrasonic vocalizations, USVs) were used to investigate toluene's acute and
long-term effects on two measures of anxiety behavior. At ten days of age,
neonatal subjects were administered toluene (1 g/kg i.p.) and USVs were
recorded. The subjects were retested as juveniles on an elevated plus maze to
examine sequela of earlier toluene exposure. Acute toluene administration
reduced USVs relative to control groups in neonates of both lines, indicating
anxiolysis. As expected, Lows had reduced USVs relative to Highs. At 28 days of
age, Highs spent more time in the open arms of the elevated plus maze than Lows.
However, prior neonatal toluene exposure blocked this reversal of behavioral
phenotype. This suggests that early toluene exposure compromised a compensatory
process occurring during this developmental period, which may have been
maternally mediated. These results have implications for the effects of early
drug exposure on plasticity in the developing nervous system.
Age-dependent Effects of Gestational and Lactational Iron
Deficiency on
Anxiety Behavior in Rats
Rosemary Eseh ’04 & Betty Zimmerberg, Professor of
Psychology
Behavioural Brain Research, 164, 214-221 (2005)
Gestational iron deficiency (ID) has been linked to alterations in GABA
neurotransmission, but whether these neuronal changes are mirrored in altered
anxiety behavior in rats is not known. In this experiment, two tests of
GABA-related affective behaviors in rats, ultrasonic vocalizations (USVs) and
elevated plus maze (EPM) were used to investigate the consequences of maternal
ID. Female rats were randomly assigned to one of three diet groups: low iron
(10-20 ppm Fe), recommended (standard) iron control (60 ppm Fe) or lab chow (250
ppm Fe) control. Diets started 7 days prior to mating and continued until 10
days after birth (PN10). Maternal behavior and offspring growth and activity
were also assessed. Blood samples taken on PN10 revealed a significant decrement
in serum iron and an increase in total iron binding capacity in the low iron
groups compared to the two control groups. Relative to the two control groups,
the low iron group weighed less on PN1, and this weight difference persisted in
adulthood. In neonates, the rate of USVs in the low iron group was significantly
higher than the two control groups, and their general activity was significantly
less than the controls. Maternal behavior was not significantly different across
groups. By adulthood, anxiety behavior and motor activity in the low iron group
were comparable to controls, although the iron deficient subjects habituated
more slowly. This study shows that prenatal iron deficiency results in increased
anxiety behavior in neonates that appears to be reversed with iron repletion but
that some aspects of altered exploratory behavior and growth persist into
adulthood.
The Effects of Selective Breeding for Infant Ultrasonic
Vocalizations on
Play Behavior in Juvenile Rats
Susan A. Brunelli, Rui Nie ’05, Clare Whipple
‘05, Vivian Winiger ‘05, Myron A. Hofer, Betty Zimmerberg, Professor
of Psychology
Physiology and Behavior. 87, 527-536 (2006)
For over 25 generations, two lines of rats (High and Low USV lines) have
been selectively bred for extreme rates of infantile (45 kHz) ultrasonic
vocalizations (USV) in response to maternal separation at postnatal day (P)10.
High and low line juveniles (P30-P40) were socially isolated and allowed to play
in same-sex sibling pairs for 10 min per day over three days. Measures of play
were nape contacts and pinning. Other social and nonsocial behaviors were also
scored during the three sessions; two of these, 55 kHz USV and walk-overs, were
statistically associated with play. Compared to the Random control line, both
High and Low line juveniles showed deficits in play behavior. In the High line,
play initiatory behavior (nape contacts) was reduced, but pinning, USV and
walk-overs were relatively unchanged. In contrast, nape contacts, pinning, USV
and walk-overs were all reduced in Low line juveniles compared to Random line
controls. The results suggest that selection for extremes of infant USV rates
has produced temperamental differences that are expressed in juvenile play in
the High and Low USV lines.
Rats Bred for High versus Low Anxiety Responses
Neonatally Demonstrate Increases in Lordosis, Pacing Behavior, and Midbrain 3
alpha, 5 alpha-THP Levels as Adults
C. Frye, K. Sumida, Betty Zimmerberg, Professor of
Psychology, & S. A. Brunelli
Behavioral Neuroscience, 120, 281-289 (2006)
Duration and intensity of lordosis is mediated by actions of the
progesterone (P) metabolite, 3 alpha-hydroxy-5 alpha-pregnan-20-one (3 alpha,5
alpha-THP) at GABA-sub(A) receptors in the midbrain ventral tegmental area.
Because rats selectively bred for infantile vocalizations may differ in
endogenous 3 alpha,5 alpha-THP secretion, their sexual behavior, midbrain, and
plasma 3 alpha,5 alpha-THP levels as adult rats in behavioral estrus was
examined. Rats bred for high rates of infantile vocalizations had shorter
latencies and intervals between intromissions and ejaculation, higher lordosis
quotients and ratings, more pacing of their sexual contacts, and had higher P
and 3 alpha,5 alpha-THP levels in plasma and midbrain than did rats bred for low
rats of infantile vocalizations. Thus, levels of 3 alpha,5 alpha-THP in the
midbrain are associated with differences in sexual behavior of these
rats.